高强钠钙铝硅系浮法玻璃组成、结构及性能的研究-study on composition, structure and properties of high strength sodium calcium aluminum silicon float glass.docx

本课题采用离子交换法对玻璃进行化学强化处理，影响离子交换的因素来源于离子浓度梯度与玻璃结构致密度对离子扩散阻碍两个方面。影响化学强化 后玻璃表面应力情况的因素主要来源于两个方面：离子交换产生的“挤塞效应” 和玻璃结构致密度对应力松弛的影响。通过离子交换法来增强玻璃机械强度， 只有当应力层厚度大于玻璃表面微裂纹的深度时，压应力克服裂纹扩展提高玻 璃强度的作用才能够得到充分显现，并且化学强化后机械强度随应力值的增大 而增大。关键词：硅酸盐玻璃，结构，粘度，离子交换，机械强度IIAbstractWith the development of modern high-rise building, automobile, information and optoelectronic industry, the high-performance flat glass are applied widely. However, as the chemical stability, mechanical and thermal property of traditional soda-lime-silicate flat glasses is not good enough, this greatly limits its application for the window, windscreen and substrate glass. Therefore, the research and development of a new float glass with higher physicochemical property is essential for the commercial flat glass. Al2O3 can improve many physicochemical properties of traditional soda-lime- silicate flat glass, such as thermal stability, chemical durability and mechanical properties. But there is some problems in the melting and forming process of this glass with high aluminum content, such as high melting temperature, larger viscosity, glass refining for a longer time, many cords and striae. The key of developing a new float glass with high aluminum content is to solve these above process problems, so the research of glass melt properties is very important.Based on the composition of traditional soda-lime-silicate flat glass, the aim of this work is to enhance the physicochemical properties of glassy products by increasing the Al2O3/SiO2 ratio and B2O3/Na2O ratio. The structure, viscosity, workability, thermal expansion, bending strength, chemical durability and weatherabiliy of glass were investigated by FT-IR, Raman spectroscopy, rotating crucible viscometer, horizontal dual-rod dilatometer, ICP-AES, optiacal and electronic microscopy. Besides, the mechanism of ion-exchange chemical reinforcing this system glass was investigated by EPMA and stress analyzer. The results show that:When SiO2 was substituted by Al2O3, increasing