高温处理对pan基碳纤维结构与拉伸性能影响-effect of high temperature treatment on structure and tensile properties of pan - based carbon fiber.docx

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 万方数据 万方数据 万方数据 万方数据 Abstract In recent years, carbon fiber reinforced resin matrix composites (CFRP) with excellent properties of the high strength, light weight and corrosion resistance is widely used in the field of civil engineering, such as the reinforcement of existing bridge structure and other components and reinforcement of the new structure. Compared with the traditional structural materials (such as steel), the performance of CFRP will deteriorate at elevated temperatures, and even burn. The fire resistance performance at elevated temperatures of CFRP is one of the important factors affecting the application in Civil Engineering. The fire resistance performance at elevated temperatures of CFRP depends on the carbon fibers and resin matrix. The field studies not only the properties evolution of high temperature of CFRP and its structure, but also concerns the performance change after experiencing fire or other high temperature extreme situations. The paper will focus on studying the post elevated temperature conditions, namely the second kinds of condition, and aiming at the properties evolution of fiber. In the elevated temperature fire, the carbon fiber of CFRP surface is in oxygen rich environment, while the carbon fiber inside CFRP may be in the anaerobic environment. Based on this analysis, this paper would adopt the two kinds of environment (air and argon), two kinds of high temperature treatment effect (time and temperature) to study the evolution rule between the structure and tensile property of carbon fiber after elevated temperature treatment, and build the mutual relationship model among the tensile properties, structure and elevated conditions(400℃-700℃) of carbon fiber. The results showed that in air environment, the mass of carbon fiber decreased rapidly with the temperature increasing, and the carbon fiber completely decomposed till to about 739℃, while in argon environment, ele