钙磷生物玻璃陶瓷涂层包覆镁合金的制备及性能分析-preparation and performance analysis of magnesium alloy coated with calcium phosphate bioglass ceramic coating.docxVIP

ABSTRACTMagnesium (Mg) and its alloys have been considered as a promising metallic material for biodegradable bone implants due to their desirable mechanical properties, biocompatibilities, biodegradabilities and bone induction ability. However, the high corrosion rate of magnesium alloys in chloride containing environment, leaded to the fast loss of mechanical integrity and the release of hydrogen, which limited their biomedical applications. Therefore, it is important to develop magnesium alloys with controllable degradabilities. Surface modification with appropriate coatings on Mg–based alloys is regarded as an effective method to reduce the degradation rate of these Mg alloys.In this work, CaO-P2O5-Na2O-ZnO glass–ceramic coatings have been successfully fabricated on AZ31 magnesium alloys through sol–gel dip–coating method. The influence of preparation parameters on the surface morphology and composition of the coating was studied by SEM, XRD and FTIR. The corrosion properties and the apatite formation of coated AZ31 magnesium alloys were also investigated by electrochemical test and immersion test. The results showed that homogeneous and crack–free CaO-P2O5-Na2O-ZnO bioglass-ceramic coatings with the thickness of ~1.00 μm were successfully fabricated on AZ31 magnesium alloys under the proper condition of sol concentration and drying. The heat treatment temperatures have a great influence on the composition and properties of coatings. As the heat treatment temperature increased from 400 °C to 500 °C, the portion of glass matrix decreased and Ca2P2O7 and Ca4P6O19 phases crystallized from the glass matrix. All the coatings fabricated at different temperatures can increase the corrosion potential and impedance of the substrate and decrease the corrosion density of magnesium alloy, improving the corrosion resistance of substrates. Particularly, Sample C400 has the lowest residual stress, displaying the slightest cracking in the immersion test, thus exhibited the lowe