新型超支化聚硅氧烷改性高性能树脂的分析-analysis of new hyperbranched polysiloxane modified high performance resin.docx

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2018-06-03 发布于上海
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新型超支化聚硅氧烷改性高性能树脂的分析-analysis of new hyperbranched polysiloxane modified high performance resin.docx

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新型超支化聚硅氧烷改性高性能树脂的分析-analysis of new hyperbranched polysiloxane modified high performance resin

ResearchonhighperformancepolymersmodifiedwithhyperbranchedpolysiloxanesAbstractResearchonhighperformancepolymersmodifiedwithhyperbranchedpolysiloxanesAbstractHighperformancethermosettingresinsareakindofpolymerswithcross-linkednetworkstructure,andhavereceivedgreatattentionsowingtotheiroutstandingintegratedproperties,showinggreatpotentialinmanycutting-edgefields,especiallyaerospace,electricandelectronicindustries.Siliconeresinsandbismaleimide(BMI)arerepresentativesofthehigh-performancethermosettingresins.Asotherthermosettingresins,theyhavehighviscosity,complexcuringprocessandpoortoughness,andthermalanddielectricpropertiesshouldalsobefurtherimproved.Hyperbranchedpolysiloxaneperformsgoodflowability,solubility,internalcavityandmultipleterminalgroups,anditalsoexhibitsmanyspacialchemicalandphysicalpropertiessuchaslowandhightemperaturestability,insulation,oxidation-resistanceandflameretardancyect.Therefore,itcanbeusedtoimprovetheperformanceofthethermosettingresineffectively.Thecontentsinvestigatedinthisthesisareasfollows:Firstofall,intraditionalsolvent-freesiliconeresinsystems,poly(methylphenylvinylsiloxane),hydrogen-containingoligomericlinearorcyclicsiliconeoilsandlinearpolysiloxaneareoftenusedasthebaseresin,reactivediluentandcross-linkingagent,respectively.Butitsviscositydoesnothavegoodstability.Hyperbranchedpolymershavebeenprovedtobeeffectivediluentsduetotheirspecialstructuresanduniqueproperties.Therefore,thehyperbranchedpolysiloxanewithSi-Hgroupscanservesasboththediluentandcross-linkingagentofsolvent-freesiliconeresins.Butthecompatibilitybetweenthetwocomponentsarepoor,whichmakesthedilutingeffectcannotbeexertedandreducesthedielectricandthermalproperties.Thehyperbranchedpolysiloxanes(MHSis)withvaryingconcentrationsofandSi-HandSi-methyl(Si-Me)groupsweresynthesizedandcharacterized,andthenaseriesofAbstractResearchonhighperformancepolymersmodifiedwithhyperbranchedpolysiloxanesMHSi/poly(methylphenylvinylsilicone)(PSi)resinswerepreparedtoinvestigatetheinfluenceofthestructuresan