新型软质pvc抗静电与阻燃改性的分析-analysis of antistatic and flame retardant modification of new soft pvc.docxVIP

验营造良好的环境。通过以上技术实施 ，样品经国家劳动保护用品质#监督检验测试中 心检测 ，在 祖度为 20.C ，相对湿度为 40%的环境条件下 ，材料表面电阻率为 2.4x 10迹，体 电 阻率为 1.3x l03Q; 参照 GB/T5455-1997 检验 ，续燃及阴燃时间为 0 秒，力学性能得 到明显改普。且经71浸炮 100 小时，材料抗静电和阻燃性能没有明显变 化。样品同 时经中科院上海应用物理研究所扫描电镜分析观察 ，纳米颗粒在高聚物 中呈优良葡 萄状网络结构分布 ，这正是材料具有优良防静电性能的根本原因。关键词: 软质 PVC; 抗静电 : 阻燃:力学 :改性课题来源: 国家自然科学基金项目 河南省高科技开发项目(豫求改高技函 [2008]236 号〉Research on anti-static and anti-igniting material for new soft PVCMajor: Condensed matter Physics Master : HuangBenbenTeacher: Professor Zhang JingchangAbstractPolyvinyl chloride(pVC) is usually poly merized by viny l chloride monomer Because of good acid resistance，alkali resistance and m echanica l strength ，it has a large amount of demand，more than 10 m illion tons every year in recent years. Soft PVC ismade by PV C added plasticizer.After being filled with modifying agent，the physicalproperties such as break stren gth ，cold-resistance are increased，soft PVC is widely used in many products and equipments. Soft PVC modified by anti-static agent and flameretardant are widely us巳d in petroleum ，natural g邸，coal，military and other special areas，and effectively prevent the disasters caused by the polymer materials and equipmentsstatic electricityThe provision of 7.2.1 in the national standard GB I2158-2006: The materialsslllface resistivity and body resistivity should below 108Q and 106Q.m in explosive environments. Whereas，the surface resistivity of the conveyor belt ，hairdryer and other anti-static m aterials is about 1011Q used in many coal min e，is 3 orders of magnitudehigher than the national standard . Althou gh this material is anti-static electricity pro臼ssed，is sti ll the static electricity disasters hidden danger. 1n th is article，the technology and process about the soft PVC modification by flame-retardant andnano-filler are introduc巳d，the anti-static electricity m odif ied by the self-made permanent antistatic agent and the ordinary carbon black added to soft PVC as