乙烯—丁烯共聚物发泡材料的制备及其结构与性能的研究-preparation of ethylene-butylene copolymer foaming material and study on its structure and properties.docxVIP

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乙烯—丁烯共聚物发泡材料的制备及其结构与性能的研究-preparation of ethylene-butylene copolymer foaming material and study on its structure and properties.docx

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乙烯—丁烯共聚物发泡材料的制备及其结构与性能的研究-preparation of ethylene-butylene copolymer foaming material and study on its structure and properties

缩回弹性能增强。本论文为研究发泡剂 AC 在实际应用环境中的分解特性提供了有效的表征方法，给出了大量的基础数据；为 ENR 发泡材料的配方与工艺设计提供了指导；为改善 LDPE 等发泡材料的压缩回弹性能开辟了新的途径，兼具理论意义和实用意义。关键词乙烯-丁烯共聚物，偶氮二甲酰胺，发泡材料，发泡特性，回弹性A Study on Preparation and Properties of Ethylene-Butene Copolymer FoamsABSTRACTPolymer foam has long been used in the field of structural, insulation and damping areas because of its excellent properties. However, the applied research on polymer foams is ahead of basic research through the years, the compounding and processing of foaming technology mostly depend on experience and plenty of experiments. Therefore, it is necessary to study the decomposition of blowing agent qualitatively and quantitatively, to study the match of blowing process between crosslinking process.Ethylene-Butene copolymer (ENR) is a new type thermoplastic elastomer polymerized by metallocene catalyst and industrially produced by DOW Chemical Company. In this paper, we selected ENR as matrix material, azodicarbonamide(AC) as blowing agent, dicumyl peroxide (DCP) as crosslinking agent. The decomposition characteristics of AC in ENR compound were determined qualitatively and quantitatively. Furthermore, the preparation and properties of ENR foam materials were studied in detail, the resilience improvement of low density polyethylene (LDPE) foam was achieved by incorporating ENR as the elastic component.At first, the ENR/AC compound was prepared by blending AC in ENR matrix in the mixer of HAKKE rheometer. The decomposition characteristics of blowing agent AC inENR were comprehensively studied by FTIR、TGA and DSC analyses. The results showthat there are three steps during the decomposition process of AC at a constant heating rate and 63.7wt% gaseous product is released from AC. The onset decomposition temperature (Tonset) of AC decreases with addition of Zinc Oxide or Zinc Stearate as activating agent in ENR matrix, the optimum ratio of AC to Zinc oxide and Zinc Stearate are 1:1 and 1:0.4 respectively. Combination of Zinc Oxide with Zinc Stear