硅基介孔质料负载型Pd、Rh催化剂及其催化性能的研究.pdfVIP

的相转移催化剂残留在孔道中，起到相转移催化剂的作用。最后催化剂对芳香酮 的不对称氢转移反应催化活性研究表明：两类负载型催化剂具有极高的催化活性 和对映选择性，在较短的催化时间转化率高达99％、ee值高达97％。其中花状颗粒 缄雠俐刊教翎1嗽罐蝣憔髁撒觥似乒嘲㈣ 关键词：负载型催化剂；芳香酮还原； suzul(i偶联反应：自组装。 Abstract and researchesand havebeendoneon more experiments catalyst， Recently，more and havecomeinto which has heterogeneouscatalyst manycatalysts being，among influencetothe andthefieldof aroundthe broughtdeep catalystchemistry chemistry the of carlnot overcome world．The only difficulty productionheterogeneouscatalyst the thelossof utilizationof carlalsoovercome of ofthe difficulty cyclic catalyst，but noble tosolvethe ofthe metal metal，which heavy pollution．The help problem onthe selectionofthecarriermaterialof has effect heterogeneouscatalystgreat selectthe willnot increasethe reaction．If material，it only catalytic you organosilicon Canalsosavethetimeof carlreachthe rateofconversion，but reaction．Therefore，we demandof waterasthemedium．Inthis greenchemistrybyusing article，the willbemadebetweenthe of