聚乙烯亚胺对纳米SiO_空心颗粒分散行为的影响.docVIP

------------------------------------------------------------------------------------------------ —————————————————————————————————————— 聚乙烯亚胺对纳米SiO_2空心颗粒分散行为的影响 第20卷第5期 高 校 化 学 工 程 学 报 No.5 Vol.20 2006 年10月 Journal of Chemical Engineering of Chinese Universities Oct. 2006 文章编号：1003-9015(2006)05-0752-07 聚乙烯亚胺对纳米SiO2空心颗粒分散行为的影响 王 青1, 文利雄1, 郑田苑2, 陈建峰1,2 (1. 北京化工大学 纳米材料先进制备技术与应用科学教育部重点实验室, 北京 100029; 2. 北京化工大学 教育部超重力工程研究中心, 北京 100029) 摘 要：采用在制备过程中添加聚电解质型分散剂聚乙烯亚胺(PEI)和在制备好的纳米SiO2空心颗粒水悬浮液中添加 PEI并球磨这两种方法对纳米SiO2空心颗粒进行分散，并对这两种方法进行了比较，最后采用以PEI作为分散剂，利 用球磨工艺，对已制备的纳米SiO2空心颗粒水悬浮液进行分散的方法，研究了PEI在纳米SiO2空心颗粒表面的吸附 行为及水悬浮液的分散稳定性。结果表明，PEI在纳米SiO2空心颗粒表面的吸附提高了颗粒间的排斥势能，改善了纳 并阐明了加入PEI后纳米SiO2空心颗粒表面ζ电位的变化趋势、不米SiO2空心颗粒的团聚问题及其悬浮液的稳定性。 同pH值下PEI在纳米SiO2空心颗粒表面的吸附量与其加入量的关系等。 关键词：纳米SiO2空心颗粒；分散性；聚乙烯亚胺；ζ电位；吸附 中图分类号：TB383；TQ027.36；TQ127.2；TQ423.92 文献标识码：A Study on the Effects of Polyethylenimine on the Dispersibility of Hollow Silica Nanoparticles WANG Qing1, WEN Li-xiong1, ZHENG Tian-yuan2, CHEN Jian-feng1,2 (1. Key Lab for Nanomaterials, Ministry of Education; 2. Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, Beijing 100029, China) Abstract: Two different methods were applied to disperse the hollow silica nanoparticles (HSNP) with polyethylenimine (PEI) as the dispersant. One method is that the PEI is used as dispersant during the preparation process of the HSNP, while the other is that, after preparing the HSNP, the PEI is added in the suspension of prepared HSNP and then the suspension undergoes milling treatment to achieve the desired dispersion. The results show that adding PEI during preparation of HSNP have no noticeable improvement for the dispersion, while adding PEI into the suspensions of prepared HSNP and un