基于有序介孔大孔二氧化硅材料的制备及其应用分析-preparation and application analysis of ordered mesoporous silica materials.docx

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2018-08-14 发布于上海
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基于有序介孔大孔二氧化硅材料的制备及其应用分析-preparation and application analysis of ordered mesoporous silica materials.docx

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基于有序介孔大孔二氧化硅材料的制备及其应用分析-preparation and application analysis of ordered mesoporous silica materials

ABSTRACTMesoporous/macroporousmaterialshavebeenextensivelystudiedduetotheirhighlyorderedandeasilycontrolledporestructure,largesurfaceareaandnarrowporesizedistribution.Thesefeaturesareofgreatinterestforvariouspotentialapplicationssuchascatalysis,adsorption,separations,andbiomedicalsystems.Moreandmorespecialistsandscholarshavededicatedtoexploretheirsynthesisandrelativeperformance.Basedonspecialcharactersthatcombininghighdiffusionofmacroporouswithhighsurfaceareaandhighporevolumeratioofmesoporoussilica,hierarchicalmesoporous/macroporoussilicamaterialshavehighaccessibilityandstoragecapacity.Inrecentyears,variouskindsoftemplatingapproacheshavebeenproposedtosynthesizehierarchicallyporoussilicamaterials.Forexample,colloidalparticles,polymers,emulsiondropletswereemployedtocreatemacroporousstructureswhilesurfactantswereemployedtocreatemesoporousstructures.However,therestillexistmanyproblemssuchastheadjustmentofbothwell-orderedmesostructureandwell-definedmorphology,controlofinteractionofdifferenttemplatesandtheimprovementofsynthesisprocess.Inthisthesis,weusethedual-templatingmethodinordertosynthesizehierarchicalmesoporous/macroporoussilicamaterialswithhigh-densitymacroporesandwell-orderedandadjustablemesopores.Subsequently,weusetheobtainedmaterialsassupporttoexploreitscatalyticperformanceinthedirecthydroxylationofbenzenetophenol.Themaincontentsareasfollows:Inthefabricationprocess,usingpolystyrene(PS)andP123astemplates,tetraethoxysilane(TEOS)asthesourceofsilicon,hierarchicalmacro-mesoporoussilicamaterialwith3-Dinterconnectedmacroporousstructures,well-orderedmesostructureandcontrolledporesizebasedpolystyrenemicrosphereshasbeensynthesized.Inaddition,weresearchintothefactorswhichinfluencetheporestructureandmorphologyofthesilicas.Irondopedmesoporous/macroporoussilicamaterials(Fe/SiO2)arepreparedviaimpregnationofmesoporous/macroporoussilicamaterialsintoironnitratenonahydrateiii(Fe(NO3)3·9H2O)solution,evaporation,andsubsequentsimplethermalcondensation.ThisexperimentusesFe/SiO2ascatal