化学文献检索与化学论文写作.pptVIP

But It’s Not Google. 但它不是谷歌。 课程讲授内容 第一章、绪论 第二章、期刊 第三章、CA 第四章、SCI和EI 第五章、论文写作 第一章 第五章 第五章 第五章 Extraction Behavior of Rare Earths in Ion Liquid Extraction System Using 1-Butyl-3-methyl-imidazolium Hexafluorophosphate and Benzoyl Acetone Zhongwei Pan1,a,*, Chang Ma2,b, Yingwu Zhang1,c, Yuxia Huang1,d, Xinglin Chen1,e, Xueping Zhang1,f 1School of Chemical and Biological Science, Quanzhou Normal University, Quanzhou, Fujian, P. R. China 2Department of Chemistry, Qinghai Normal University, Xining, Qinghai, P. R. China azhongweipan@, bqhxn_mach@, czhyw502@, dhuangyuxia@, exinglinchen@, fzhangxueping@ *correspondence author Keywords: Ionic liquid, Benzoyl acetone, RE3+, Extraction Abstract. The extraction behavior of five rare earth ions (RE3+) was investigated in ionic liquid (IL) extraction system using 1-butyl-3-methyl-imidazolium hexafluorophosphate ionic liquid ([Bmim]PF6) as extraction solvent and benzoyl acetone (HA) as extractant. The extraction percentage of RE3+ using [Bmim]PF6 was less than 8% without HA. When sufficient HA was included in IL phase, the extraction percentage of RE3+ could be higher than 98%. The extracted species in the RE3+-[Bmim]PF6-HA system was neutral REA3 and the recovery of RE3+ extracted into [Bmim]PF6 can be achieved using the mixture of hydrazine hydrate and ethylenediamine tetraacetic acid (EDTA) as stripping agent. [Bmim]PF6 can be recycled in the experiment. Introduction Ionic liquids (ILs) are salts with a melting point close to or below room temperature. They form liquids composed of the majority of ions. This characteristic makes these materials behave very outstanding properties when they are used as solvents compared to conventional molecular liquids. So far ILs have attracted much attention as novel solvents [1~5]. Some water-immiscible ILs can be used as excellent extraction solvents for liquid-liquid extraction of metal ions. Unlike conventional extraction solvents such as hydrocarbons, ketones, ethers and alcoh