毕业论文 UV Fenton法处理造纸黑液的研究.docVIP

毕业设计（论文） UV/Fenton法处理造纸黑液的研究 摘要 　　在这个实验中测试了不同pH值时紫外光助Fenton法（UV/Fenton）pH值对造纸黑液COD去除率的影响也进行了评测。COD（化学需氧量）和BOD5（5日生化需氧量）被选为评价Fenton法和光助Fenton法这种高级氧化法（AOPs）pH= 10.8，CODo = 126631.8 mg/l， BOD5 = 490 mg/l）。在合适的反应条件下（[Fe2+] = 3g/l， [H2O2] = 5 ml/l，pH = 5， =150min），采用光助Fenton法处理造纸黑液可获得79.14% 的COD去除率。光助Fenton法处理造纸黑液的另一个优点是可以提高黑液的可生化性，处理后BOD5/COD值从0.0039提高到0.24228，上升了62倍多。从以上的实验结果可推出光助Fenton法是处理造纸黑液的一种合适方法。光助Fenton法产生处理效果主要是靠反应过程中生成的非常活跃的氧化性自由基－羟基自由基·OH。羟基自由基·OH能够逐渐氧化分解难降解的人工合成化合物和天然的有机混合物，甚至最终把它们都氧化成CO2和H2O，这都要归功于它在水溶液中的高氧化电极电位（+2.80 eV）UV/Fenton，COD去除率，可生化能力 Research in UV/Fenton treatment of black liquor Abstract In this study, the degradation of black liquor by UV light assisted Fenton-like process (Fe2+/H2O2/UV-A) have been investigated at pH = 5. The effects of different process variables such as the initial Fe2+and H2O2 concentrations, 　reaction time and UV-A light on black liquor COD(Chemical oxygen demand) removal have been evaluated. Chemical oxygen demand (COD), 5-day biochemical oxygen demand (BOD5) were selected as the environmental sum parameters to follow the performance of Fenton-like and photo-Fenton-like advanced 　oxidation processes (AOPs)on the black liquor (pH= 10.8,CODo = 126631.8 mg/l; BOD5 = 490 mg/l). At optimum reaction conditions (i.e. [Fe2+] = 3g/l, and [H2O2] = 5 ml/l, pH = 5 reaction time=150min), 79.14% COD removal where achieved by the photo-Fenton-like process. The another superiority of the UV-A light-assisted Fenton-like process over the black liquor was more evident in terms of its effect on biodegradability improvement; the BOD5/COD ratio increased from 0.0039　to 0.24228　which is 62 times than start after application of the photo-Fenton-like processes。Based on the results of above experiments it could be inferred that the photo-Fenton-like process is a suitable method for partial mineralization of black liquor. he photo-Fenton-like processes rely on the generation of very reactive oxidizing agents, i.e.