反应温度对水性丙烯树酯性能的影响毕业论文.docVIP

本科毕业论文（设计） 题 目： 学 生： 学号： 201040720136 学 院： 化学化工学院 专业： 应用化学 入学时间： 2010 年 9 月 13 日 指导教师： 职称： 教授 完成日期： 年 月 日 剽窃他人的学术观点、思想和果 摘要：本论文主要阐述温度对水性丙烯酸树脂性能的影响。实验以甲醇为溶剂，以乙烯基三乙氧基硅烷与甲基丙烯酸甲酯、丙烯酸丁酯、甲基丙烯酸羟乙酯以及丙烯酸等单体共聚,偶氮二异丁腈为引发剂、二甲基乙醇胺为中和剂，通过自由基溶液聚合方法进行共聚合反应,分别合成出温度在60℃、65℃、70℃、75℃、80℃时的水性丙烯酸树脂并对其所制备的漆膜性能以及性能进行测定。水性丙烯酸树脂是一种低挥发性有机化合物的绿色环保型产品，具有较好的光泽度、耐候性、耐化学品性和稳定性高等的特点丙烯酸树脂及其涂料的性能主要表现在外观、固含量、硬度、附着力、抗冲击力和耐水性等几个方面，本实验着重研究水性丙烯酸树脂以上种性能及固化剂对它的种性能的影响。研究结果表明：反应温度在75℃时合成的丙烯酸树脂性能最佳，外观，固含量高、硬度达H、附着力、抗冲击力g的砝码于高处自由落体、耐水。把合成的丙烯酸树脂及其涂料与固化剂以适当比例混合后，通过测定获得的性能与之前相比效果更附着力抗冲击g的砝码于高处自由落体关键词：丙烯酸树脂；水性；溶液聚合；涂料；Abstract: This thesis mainly and the effect of reaction temperature on the properties of water-based acrylic resin. Experiment with methanol as the solvent, vinyl triethoxy silane and methyl methacrylate (mma), butyl acrylate, methyl hydroxy ethyl acrylate and acrylic acid monomer copolymerization, azodiisobutyronitrile as initiator, dimethyl ethanolamine as neutralizer, copolymerization reaction by free radical solution polymerization method, respectively, in the synthesis temperature 60 ℃, 65 ℃, 70 ℃, 75 ℃, 80 ℃ when the water-based acrylic resin and the preparation of paint film properties and paint film properties were determined. Water-borne acrylic resin is a kind of low volatile organic compounds of green environmental protection product, good gloss, weatherability, chemical resistance character and the characteristics of high stability. Acrylic resin and the performance of the coating is mainly manifested in appearance, solid content, viscosity, hardness, adhesion, impact resistance and water resistance and so on several aspects, this study focuses on more than seven kinds of waterborne acrylic resin coatings properties and curing agent on the properties of its seven. The research results show that the reaction temperature at 75 ℃ synthesis of acrylic resin for best performance, good appearance, solid c