敏化剂含量对乳化炸热分解性能的影响 毕业论文.doc

本科毕业设计说明书 敏化剂含量对乳化炸药热分解性能的影响 SENSITIZER CONTENT INFLUENCE ON THERMAL DECOMPOSITION OF EMULSION EXPLOSIVE 学院（部）： 专业班级： 学生姓名： 指导教师： 敏化剂含量对乳化炸药热分解性能的影响 摘要 炸药的热分解是炸药缓慢化学变化的重要形式，在乳化炸药的乳化过程中，乳化基质温度高达100℃，是乳化炸药的安全生产的隐患之一；因此，研究乳化炸药的热分解对于其安定性、热爆炸以及工艺条件的确定等均有重要意义。膨胀珍珠岩是一种常用的敏化剂，它能为乳化炸药提供有效的热点，本文用差示扫描量热仪(DSC-TGA)测试了相同升温速率下不同含量膨胀珍珠岩的乳化炸药放热分解反应的起始温度和峰顶温度，研究了膨胀珍珠岩对乳化炸药热分解的影响。随着升温速率的增加，炸药起始热分解温度增大；随着升温速率的增加，炸药热分解所达到的峰顶温度也呈增大趋势。DSC峰温与初始分解温度之差，在一定程度上反映热分解加速趋势的大小。差值愈小，加速趋势越大。根据含AL5%，膨胀珍珠岩2%的乳化炸药和AL5%，膨胀珍珠岩3%乳化炸药在不同温度加速速率下得知，在不同加速温度下，含AL5%，膨胀珍珠岩2%的乳化炸药的温差均小于含AL5%，膨胀珍珠岩3%乳化炸药的温差，含AL5%，膨胀珍珠岩3%乳化炸药的热分解性能较好。 关键词：乳化炸药，膨胀珍珠岩，热分解，反应动力学 SENSITIZER CONTENT ON THE THERMAL DECOMPOSITION OF EMULSION EXPLOSIVE PERFORMANCE INFLUENCE ABSTRACT Thermal decomposition of the explosives is a type of slow chemical change form. In the production process of emulsion explosive , temperature of emulsion matrix has reached as high as 100℃, high temperature is emulsifies one of explosive safety in production hidden dangers； Therefore, researching characteristics of thermal decomposition of the emulsion explosive have important significance on its stability, the thermal explosion as well as the technological conditions. The expanded perlite is often The sensitizer has important influence on thermal decomposition characteristics of the emulsion explosive. Has tested under the same elevation of temperature speed with the differential scanning calorimetry meter (DSC-TGA) different content expansion perlite emulsified blasting explosive exothermic decomposition reaction initial temperature and the peak temperature, studied the expansion perlite to emulsify the blasting explosive heat-resistant quality influence.As the heating rate increased, the thermal decomposition temperature of explosive initiation is increased; as the heating rate increased, the thermal decomposition temperature of the peak is also increasing trend. DSC