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Analysis of Soil in the Field using
portable FTIR
A H Jean Robertson, H Rachael Hill,
Angela M Main
International Workshop “Soil Spectroscopy: the
present and future of Soil Monitoring” FAO HQ,
Rome 4-6 December 2013
FTIR of Soil
• An FTIR (Fourier Transform Infrared) spectrum in the mid infrared (MIR)
region, produced when infrared radiation is absorbed by a soil sample, gives
the overall chemical profile of the soil
• Importantly, FTIR spectra can provide information about both the organic and
mineral components of the soil
• Absorption bands in the IR spectrum (4000 to 400 cm-1) relate to
fundamental vibrations of the functional groups present in the sample
e
c
n
a
t
t
i
m
s
n
a
r
T Nontronite
%
1
Frequency (cm- )
Interpretation of an FTIR spectrum of Soil
The IR spectrum of a soil sample can be readily interpreted to give
information on the nature and proportions of the soil organic
matter and the minerals present
FTIR or NIR for soil analysis?
NIR spectrum
• To date, the NIR
spectral range, with
diffuse reflectance
spectra, has been
more widely
developed than the
FTIR technique using
Albic histic Podzol
the MIR range
• It is seen as being
cheaper and having
technology that is
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