化学反应速率（Chemical reaction rate）.docVIP

化学反应速率（Chemical reaction rate） The seventh chapter is chemical reaction rate Home page Problem analysis Student self-test Student self test answer Exercises answers after chapter Problem analysis [TOP] The reaction mechanism of 7-1 HNO2 decomposition is as follows: the expression of rate equation for total reaction is obtained. The reaction rate is determined by the rate control step. Solution, = = v Example 7-2 shows that the time required for the first order reaction to complete 99.9% is approximately 10 times the half life. Solution t1/2 = 0.693/ K Case 7-3 is based on the relevant data of gas phase reactions T (K) 600645 K (L2? Mol-2m? IN-1) 6.62? 1056.81? 105 K (L? Mol-1? Min-1) 8.40 40.8 (1) the equilibrium constant at two temperatures. (2) activation energy of forward and reverse reactions. When (1) 600K, 640K time, (2) activation of positive reactions = =2.02 kJ? Mol-1 Activation energy of reverse reaction = =113.0 kJ? Mol-1 Students self test questions, [TOP] judgment questions, multiple-choice questions, cloze questions and answers A determine the problem (to the tick, wrong x) The 1. chemical reaction rate constant kA is related to the concentration of reactants. () 2. for the reaction, the reaction rate constant always increases with the increase of temperature. () 3. in the rate equation, the index of the concentration of each substance is equal to the coefficient before the chemical formula in the reaction equation, and the reaction is a meta reaction. () 4. the law of mass action applies only to meta reactions. () 5. reaction N2 (g) +3H2 (g) - 2NH3 (g), because N2, H2 and NH3 are in the same phase, so the catalytic action of the catalyst is homogeneous catalysis in this reaction. () Two, select the question (choose the correct answer of each item) [TOP] 1. the reaction rate of 2ICl (g) +H2 (g) - I2 (g) +2HCl (g) is proportional to the primary of ICl concentration and the H2 concentration once. So the reaction is () A. three molecular reaction, three s