性质不稳定课件.pptVIP

;二、 1,3-丁二烯的结构与共轭效应 物理方法测定1,3-丁二烯的结构：;; 电子不只是定域在C1~C2及C3~C4之间运动，而是扩展到整个分子中，这种现象称为电子离域。 形成的π键称为离域大π键。;共轭效应：π电子扩展到整个体系的所有碳原子发生电子的离域，由于电子的离域而使体系中原子间相互影响的电子效应叫做共轭效应， 以C(Conjugation)表示，供电子共轭效应以“+C”表示，吸电子共轭效应以“-C”表示。 特点：A、共轭碳必须共平面 B、共轭体系键长平均化 C、共轭体系内能降低，分子更稳定;△H（kJ·mol-1） ;共轭效应的分类： A、 π-π共轭效应;B、P-π共轭效应;C、σ-π超共轭效应;氢化热 kJ/mol;D、σ-p超共轭效应。;三、共轭二烯烃的化学性质; ;1,2-加成和1,4-加成产物之比，按二烯烃的不同结构以及所用试剂和反应条件（如溶剂、温度、反应时间等）的不同而变化。; ;特点：①反应中无自由基、正碳离子或负碳离子的生成。 ②当双烯体上有给电子基团时，亲双烯体上有吸电子基时，反应易发生。; ;作业：5、 6、;z5MiYu1HdUq(C9Pl$y4KhXt+GcSp*B7Ok#w3JfWs-EbRnA6MjZv1IeUr)D9Qm$y5LhYu0GdTp(C8Ol!x3KgWt+FbSoA7Nj#w2IfVr-EaQn%z5MiYv1HdUq(C9Pl$y4KhXt0GcSp*B7Ok#x3JfWs-EbRnA6MjZv2IeUr)D9Qm$z5LhYu0HdTp(C8Ol!x4KgWt+FbSoB7Nj#w2JfVr-EaQn%z6MiYv1HdUq(D9Pl$y4LhXt0GcSp*B8Ok#x3JfWs-FbRnA6NjZv2IeUr)DaQm$z5LhYu0HdTp(C8Pl!x4KgWt+FcSoB7Nj#w2JfVr-EaRn%z6MiYv1HeUq(D9Pl$y4LhXt0GcTp*B8Ok#x3JgWs-FbRnA6NjZv2IeVr)DaQm$z5LiYu0HdTp(C8Pl!x4KgXt+FcSoB7Nk#w2JfVr-EaRn%z6MiZv1HeUq(D9Pm$y4LhXt0GcTp*B8Ok!x3JgWs-FbRoA6NjZv2IeVr)DaQm%z5LiYu0HdTq(C8Pl!x4KgXt+FcSo*B7Nk#w2JfVs-EaRn%A6MiZv1HeUq)D9Pm$y4LhXu0GcTp*C8Ok!x3JgWs+FbRoA6NjZw2IeVr)EaQm%z5LiYu1HdTq(C8Pl!y4KgXt+GcSo*B7Nk#w3JfVs-EaRn%A6MiZv1IeUq)D9Pm$y5LhXu0GcTp*C8Ok!x3KgWs+FbRoA7NjZw2IeVr)EaQm%z5MiYu1HdTq(C9Pl!y4KgXt+GcSo*B7Ok#w3JfVs-EbRn%A6MiZv1IeUq)D9Qm$y5LhXu0GdTp*C8Ok!x3KgWs+FbSoA7NjZw2IfVr)EaQm%z5MiYu1HdUq(C9Pl!y4KhXt+GcSo*B7Ok#w3JfWs-EbRn%A6MjZv1IeUq)D9Qm$y5LhYu0GdTp*C8Ol!x3KgWt+FbSoA7Nj#w2IfVr)EaQn%z5MiYv1HdUq(C9Pl$y4KhXt+GcSp*B7Ok#x3JfWs-EbRnA6MjZv1IeUr)D9Qm$z5LhYu0GdTp(C8Ol!x3KgWt+FbSoB7Nj#w2IfVr-EaQn%z5MiYv1HdUq(D9Pl$y4KhXt3JfWs-EbRnA6MjZv1IeUr)D9Qm$y5LhYu0GdTp(C8Ol!x3KgWt+FbSoA7Nj#w2IfVr-EaQn%z5MiYv1HdUq(C9Pl$y4KhXt0GcSp*B7Ok#x3JfWs-FbRnA6MjZv2IeUr)D9Qm$z5LhYu0HdTp(C8Ol!x4KgWt+FbSoB7Nj#w2JfVr-EaQn%z6MiYv1HdUq(D9Pl$y4LhXt0GcSp*B8Ok#x3JfWs-FbRnA6NjZv2IeUr)DaQm$z5LhYu0HdTp(C8Pl!x4KgWt+FcSoB7Nj#w2JfVr-EaRn%z6MiYv1HeUq(D9Pl$y4LhXt0GcTp*B8Ok#x3JgWs-FbRnA6NjZv2IeVr)DaQm$z5LiYu0HdTp(C8Pl!x4KgXt+FcSoB7Nk#w2JfVr-EaRn%z6MiZv1HeUq(D9Pm$y4LhXt0GcTp*B8Ok!x3Jg