光功能稀土氟化物纳米粒子的水热合成 - 材料合成化学专题讲座课件PPT.ppt

光功能稀土氟化物纳米粒子的水热合成 Outline Transition of the Inner-shell 3d electron Linear emission peak and highly monochromatic Long lifetime of the excited state ion Nonlinear optical effects Luminescence characteristics and applications Luminescence characteristics and applications Advanced display Solar Cells Biological Labeling Ethanol Stiring Stiring Ethanol Ligand(Oleic acid) Deionized water A basic hydrothermal reaction F source (NaF/ NH4F) Re source(Re(NO3)3) Effect of NaF content on the nanocrystals Reaction condition: 1.2g NaOH,9ml H2O,7ml C2H5OH, 20ml Oleic acid and temperature 160℃, time 8h Re(NO3)3(0.5M) NaF(1.0M) Figure shape 1.2ml 2.4ml Irregular nanoparticles,d≈7nm 1.2ml 3.0ml Nanocubes,d≈10-13nm 1.2ml 6.0ml Nanocubes,d≈10-13nm Ref: Leyu Wang and Yadong Li,Chem.Mater.2007,19,727-734 Effect of the Synthetic Temperature and Time Reaction condition:1.2gNaOH,5mlH2O,7mlC2H5OH,20mlOleic acid Re(NO3)3(0.5M) NaF(1.0M) T(℃) T(h) Figure shape 270μl 8ml 210 20 nanorods, d≈15-20 nm, l≈100-150nm 270μl 8ml 180 20 nanorods, d≈20 nm, l≈500-600nm 270μl 8ml 180 8 nanocubes, d≈10nm Ref: Leyu Wang and Yadong Li,Chem.Mater.2007,19,727-734 SEM images of rare-earth fluoride prepared hydrothermally at 230 ℃ for 12 h. Tube-like nanocrystals. The compositions of the mixture were NaF: Re(NO3)3: oleic acid: NaOH: ethanol: H2O =4.2: 1: 22.6: 17.5: 217: 556 (in molar ratio). Ref: Fan Zhang and Dongyuan Zhao, Angew.Chem.Int.Ed.2007,46,7976–7979 Effect of NaF content and Ph value Disk-like nanocrystals. The amount of NaOH reduced to half while the other conditions remained the same. Rod nanocrystals. The amount of NaF increased to 1.5 times, with the other conditions unchanged. Schematic diagram of the proposed process for the formation of arrays of NaYF4 nanocrystals. The formation process of NaYF4 nanocrystals Ref: Fan Zhang and Dongyuan Zhao, Angew.Chem.Int.Ed.2007,46,7976–7979 TEM characterization of NaYF4 nanocrystals doped with various concentrations of Gd3+ ions Effect of Gd3+ dopi