化工热力学-期中复习题.pptVIP

习题课 Application of Gibbs-Duhem Equation 1.For a particular binary solution at constant T and P, the partial molar volume for species 1 and 2 are presented by the following equations: Where V1 and V2 are the molar volume of pure species 1 and 2, and the a and b are functions of T and P. Show whether these equations are true with the thermodynamic theory. Gibbs-Duhem Equation的应用 1.有人提出用下列方程组来表示恒温、恒压下简单二元体系的偏摩尔体积： 式中：V1和V2是纯组分的摩尔体积，a, b只是T, P的函数。试从热力学的角度分析这些方程是否合理？ Application of Gibbs-Duhem Equation const T, P: Application of Gibbs-Duhem Equation Solution property — Partial molar property 2. For a gas mixture the volume is given by: where b is the function of composition only, and where bi is independent of P and composition. Find the expressions for the following variables. (1) , (2) , (3) , (4) . 溶液性质—偏摩尔性质 2.某类气体的容量性质由下式表示: 式中b为组成的函数。对于混合物: i组分的b值为bi，与P，x无关，试推导下列表达式: (1) , (2) , (3) , (4) . Solution property — Partial molar property Solution： (1) The following equation has been developed in proceeding courses: Solution Solution Solution Solution Thermodynamic properties 3. Justify(证明): Solution: where Heat capacity ig： rg : Heat capacity * * These two equations are not true. *