离子液体的应用及合成.ppt

hydrogen-bond interactions acidic hydrogen atoms π-πinteractions dispersivetype interactions Factors of driving extractions * the Ils’extraction ability through a range of ionic liquid concentrations. Content in the study * K of caffeine and nicotine in different ILs/ K3PO4 ABS at 298 K, with K3PO4 at 15 wt% and different wt% of ionic liquid. * The results indicate that there seems to be an optimum value for the ionic liquid concentration above which the partition coefficients start to decrease This maximum of partition coefficients is probably related to salting-out effects of the ionic liquid over the solute. * The direct extraction of alkaloids from a synthetic biological sample—artificial human urine Content in the study * K of caffeine and nicotine in different ABS at 298 K. All ABS contain 25 wt% of ionic liquid and 15 wt% of K3PO4, except the case of [OHC2mim]Cl in which its concentration is 40 wt%. * The results show that with human urine samples the extraction performances of both alkaloids are significantly improved. The presence of a more complex matrix, which now includes NaCl and urea, favours the alkaloids partitioning for the IL-rich phase. exception :the system containing the [C4mim][CF3SO3] ionic liquid, the value of K is decreased. * Compared to conventional liquid–liquid or solid–liquid extractions, this new approach avoids the use of volatile organic solvents, replacing them with relatively smallamounts of (recyclable) ionic liquid solvents in a second aqueous phase. Conclusion * Synthesis of ionic liquids expensive facilitate the general acceptance of ionic liquids Convenient synthesis of various ionic liquids is in need * Convenient synthesis of various ionic liquids from onium hydroxides and ammonium salts Tetrahedron Letters .2009, 50,4286–4288 * The main idea Hydroxide ionic liquids, such as 1-alkyl-3-methylimidazolium hydroxides, undergo smooth anion metathesis with ammonium salts to produce a variety of ionic liquids in excellent