锂离子电池安全问题研究SafetyIssuesInLithiumIonBattery(LIB)-材料合成化学课件教学.ppt

3.2.1 CV(循环伏安曲线) 3.2 Electronic performance 3.2.2 P-CC-C（电池循环性能曲线） 3.2.3 EIS(电化学阻抗) 3.2.4 C-T电导率曲线 Contents What We Can Do 4 Introduction To LIB 1 Synthesis Method 2 Problems in LIB 3 Forecast 5 Safety vents- Thermal fuses- Other circuit breakers- open in response to a sudden increase in cell pressure, allowing gases to escape the one shot fuse which is a wire of a fusible alloy with resistance and thermal characteristics that allow it to melt when a pre-set current flows through it magnetic switches, bimetallic thermostats and electronic protection circuit modules : protect power packs and to monitor their temperature Factors play a role in the operation of the devices that involve limiting the current passing through them 4.1 Conventional safety devices Separators for lithium-ion batteries are polyolefin microporous films such as PE,PP,or their drawers. If the cell temperature rises abnormally because of an excessive overcharge, for example, the heat generated softens PE and closes the micropores in the film, thus ionic transport between the electrodes is effectively stopped and current ceases to flow. 4.2 Shutdown separators Ceramic PTC materials operate under high voltages and can return to their normal resistance mode with great accuracy Conductive-polymer PTC devices At elevated temperatures, the polymer’s structure changes to an amorphous state. The accompanying expansion of the matrix breaks the conductive pathway between the embedded particles, rapidly increasing the device’s resistance by several orders Emerged safety devices called positive temperature coefficient devices based on materials whose resistance increases dramatically with a rise in temperature 4.3 Self-resetting devices physical char-forming process chemical radical scavenging process Fluorinated compounds organophosphorus compounds Main components of SEI: decomposed products of electrolyte Scheme 123 Reduction-type additive Reaction-type additive Non-flammable electrolytes Over