酚醛环氧环氧树脂复合涂层老化性能研究.docVIP

酚醛环氧/环氧树脂复合涂层抗老化性能研究 [摘要]为探讨涂层的抗老化性能，采用法在Q235碳钢表面制备了所需涂层，用紫外老化箱对其加速老化。采用电化学测试详细分析了不同辐照阶段涂层阻水性能的变化，结合红外光谱和慢正电子束分析对紫外辐照下涂层化学结构的变化进行了合理推测。结果发现，涂层阻水性能优异，且辐照前中期(528小时)涂层的结构相对稳定；紫外线吸收剂添加后涂层抗老化性能大幅提高，在辐照后期(864h)，添加量为1.5 wt%时，阻水性能达到最佳，浸泡20天后涂层低频阻抗依然保持在109 Ω(cm2。 [关键字] 酚醛环氧；紫外老化；慢正电子束；电化学交流阻抗 [Abstract] To explore the aging resistance of novolac epoxy resin/epoxy resin composite coating，the required coating was prepared on the surface of Q235 carbon steel by dip-pulling method，then it was accelerated aging by ultraviolet aging box. The changes in different irradiation stages of coatings were analyzed in detail by electrochemical test, using infrared spectrum and slow positron beam to conduct logic speculation on the surface chemical structure of coating by UV exposing. It was found that water resistance of coating was excellent, and he structure of the coating was relatively stable at early and mid-irradiation (528 h); the anti-aging performance of coating increased significantly after adding addition of ultraviolet absorption: the performance of water resistance was the best and low-frequency impedance of coating still remained 109 Ω·cm2 after soaking 20 days under the condition of later irradiation period (864 h) and the adding amount was 1.5 wt %. [Key words] novolac epoxy resin；ultraviolet aging；slow positron beam；electrochemical impedance spectroscopy [文献标识码]A [中图分类号]TQ317.6 0前言 环氧树脂由于性能优异且生产成本较低，在长效防腐涂层领域有较为广泛的应用。然而，由于自身耐候性能相对较差，在室外环境下极其容易老化，在紫外辐照下，光能会部分转变为热能与环境中的热量共同引发环氧固化结构的热老化而相关研究表明，加入适量的酚醛环氧树脂(novolac epoxy resin, EPN)和紫外线吸收剂可以有效地提高其耐老化性能[1-3]。目前对环氧涂层的光老化研究主要集中在紫外辐照条件下化学结构的变化上面如酰胺基团的生成碳氮等化学键的断裂以及羧酸等含有羧基基团的结构产生等涂层在辐照过程中不仅会发生化学结构的改变，阻水性能也会有明显的改变，而涂层的阻水性能与性能息息相关因而研究涂层在紫外老化条件下的化学结构和阻水性能的变化对研究涂层防护机制的失效及涂层的使用寿命有重大的意义现今对涂层紫外辐照下的阻水性能变化研究相对较少故本考察了涂层在UV-B辐照条件下的化学结构及性能变化规律紫外线吸收剂UV-531的加入对涂层抗老化性能的影响以期紫外辐照下的环氧树脂涂层抗老化性能延长其使用寿命。 1实验 1.1基材前处理 基材为Q235碳钢，尺寸为80 mm × 50 mm × 1 mm，先后用360、800、1200目砂纸C)对基板打磨，接着依次用酒精、丙酮对基板进行清洗，涂层涂覆后，将基材放入烘箱，80处理3h。 1.2涂层制备 制备含不同质量分数531（紫外吸收剂）的环氧将环氧树脂