锌层重量对球墨铸管防腐效果影响.docVIP

锌层重量对球墨铸管防腐效果的影响 焦俊1，陈名佶1，陈锋1，Gérard NOUAIL2，孙恕3，宋书燕4，薛纪二5 （1. 东南大学材料科学与工程学院，南京 211189； 2. 圣戈班穆松桥研发中心，法国； 3. 圣戈班管道系统有限公司（中国），马鞍山 243052； 4. 中国水协管道物资部，北京 100055； 5. 中国农业机械化科学研究院工艺材料研究所，北京 100083） [摘 要] 采用电化学“二电极”方法，定期测定三种重量喷锌层（90、130和200 g/m2）的球墨铸铁管样品在5 g/L NaCl溶液中电位的变化规律，并观察样品首次出现红锈的时间。试验发现，随喷锌层重量增加，其对球墨铸铁管基体的防腐效果呈非线性改善。比较三种锌重的相对保护周期，并考虑喷锌成本，建议球墨铸铁管采用200g/m2的喷锌工艺。 [关键词] 喷锌；球墨铸铁；防腐 [中图分类号] TG143.5 [文献标识码] A Effect of the weight of zinc coating on the anticorrosive behavior of ductile cast iron pipes JIAO Jun1，CHEN Ming-ji1，CHEN Feng1，Gérard NOUAIL2，SUN Shu3，Song Shu-yan4，XUE Ji-er5 （1. School of Materials Science and Technology, Southeast University, Nanjing 211189, China; 2. Saint-Gobain PAM Research Center, France; 3. Saint-Gobain Pipelines Co., Ltd, Maanshan 243052, China; 4. CEW of China Water Supply Association, Beijing 100055, China; 5. Chinese Academy of Agricultural Mechanization Sciences, Beijing 100083, China） ABSTRACT：Ductile cast iron pipe samples coated with three kinds of weight of zinc (90,130 and 200 g/m2) were immersed in 5 g/L NaCl solution, the evolution of the electrochemical potential of the samples was measured periodically by using electrochemical “two-electrodes” technique. Also, the time to first red rusting was recorded. It was founded that the anticorrosive performance of the samples was enhanced non-linearly with the increase of the weight of zinc coating. Considering the relative duration of galvanic protection by different weight of zinc coatings and the cost of zinc coating process, it was suggested that the proper weight of zinc coating for ductile cast iron pipes was 200 g/m2. KEY WORDS： zinc coating; ductile cast iron; anticorrosive 0 前言 锌作为一种典型的牺牲阳极的阴极保护材料，目前已经广泛应用于球墨铸铁管的外表面防腐[1-3] 。按照ISO8179-11995和GB/T17456标准130 g/m2，而欧洲标准EN545:2002则要求锌层重量≥200 g/m2) [1-2]。 目前，国内球墨铸铁管厂家主要采用涂层隔离防护（涂沥青等）与阴极保护（喷锌等)相结合的工艺技术进行外防腐。我国有些球墨铸铁管的使用单位没有意识到喷锌层防腐的重要性，为节省投资，喷锌量不足，甚至人为地省去喷锌层[1]。 国内外在喷锌防腐的应用方面已做了大量研究工作，主要集中在钢闸门、给排水阀门、水工金属结构及电器产品方面等等