丙烯酰胺光致聚合物的制备及全息存储性能优化分析-preparation of acrylamide photopolymer and optimization analysis of holographic storage performance.docx

AbstractThe high density volume holographic storage technique is one of the most promising candidate for the next generation of information storage with high storage capacity and speed transmission, now many researchers are trying their best for the optical holographic storage materials, aiming to find a best recording material to accomplish the actual application of optical holographic storage. During recent years, the photopolymer has attracted many attentions due to its high sensitivity, high signal–to-noise ratio, high storage capacity and simple preparation, not post-process. As an excellent photopolymer, poly (vinyl alcohol)-acrylamide (PVA/AA) material is widely studied due to its high diffraction efficiency, fast response, simple preparation and low cost, thus this photopolymer has good research and application values. The PVA/AA photopolymer has received many researches on its holographic performance, however its application for memory is limited by some drawbacks, such as the impact of grating attenuation on the effect optical thickness, reduces the storage ability, limits the whole performance of the holographic storage system. Consequently it is a significant investigation for improving properties of the PVA/AA photopolymer and enhancing its holographic performances. In this paper, with improvements both in material component and fabrication method, new photopolymers based on AA having good holographic performance are prepared. The photochemical dynamics of the material is investigated in detailed, and new dynamic parameters are introduced to describe the photochemical reaction. In the multilayer PVA/AA photopolymer, the storage capacity is enhanced, and its holographic performance is investigated theoretically and experimentally. These studies provided significant foundations for holographic development in actual application.With solution of PMMA, AA, TEA and MB in THF, a new photopolymer of PMMA/MAA/AA with thickness of 1.8 mm is prepared, which exhibi