变形医用镁合金在hank’s模拟体液中的腐蚀行为研究-corrosion behavior of wrought medical magnesium alloy in hank s simulated body fluid.docxVIP

AbstractMagnesium and magnesium alloys as metal-based bio-medicalmaterial is subjected to widespread concern in recent years. Magnesium alloys have broad prospects in the medical field. However, the plastic deformation of the alloy is not easy. And the corrosion resistance of this kind of alloy is poor. This paper chose alloying elements Zn and Ca which is beneficial to humans as alloy component refining the Mg-1Zn-xCa (x = 0.25,0.5) alloy, The purpose is to explore the effects of different deformation conditions on the corrosion resistance of magnesium alloys.This experiment take Mg as solvent, Zn and Ca as solutet. Two kinds of degradable ternary Mg-1Zn-xCa alloys with Ca contents of 0.25% and 0.5%, were fabricated by the protection of the flux method. Doing the extrusion deformation experiments of Mg-1Zn-xCa alloys with Ca contents of 0.25% and 0.5% are subjected different extrusion pressure. The Deformation rate of this alloy is 0, 6%, and12%. Do corrosion experiment atconstant temperature 37℃, taking the different deformed magnesium alloys for corrosionmaterials and simulated body fluid as aggressive medium. Corrosion time from 0 to 32 days. Study the influence that different deformation rate to Mg-1Zn-Ca(x=0.25,0.5) alloy organization and corrosion resistance, using microstructure observed, Macro corrosion observed, determination of the corrosion rate and electrochemical analysis method.The microstructure experimental results show that Mg-1Zn-xCa(x=0.25,0.5) alloys grain were refining with the increasing of deformation rate(0,6%,12%).Alloys composition include α interstitial, MgZn and Mg2Ca; Macro corrosion morphology showed thatcorrosion resistance of Mg-1Zn-0.25Ca subjected 12% is best ； The corrosion rate ofcorrosion test indicated that corrosion rate of Mg-1Zn-0.25Ca alloys subjected 12% is slowest, its average corrosion rate is 4.07×10-3g.cm-2.d-1. The average corrosion rate of it in casting condition is about 6 times. The corrosion resistance