丙烯酰胺系均聚物和共聚物反相乳液的合成分析-synthesis and analysis of acrylamide homopolymer and copolymer inverse emulsion.docxVIP

bestsynthesizetechnicscondition:w(AM)=40~45%;m(oil):m(water)=1.1;w(Span-80)=92%(Span-80/Tween-80 as complex emulsifiers); w((NH4)2S2O8)=0.6%;systempH=9.0;temperature70℃;w(AM):massfractionofAMinAA;w((NH4)2S2O8): mass fraction of ammonium per sulfate in AM and AA; product viscidity: 3.28Pa·s. We had also analyzed and characterized copolymer P(AM/AANH4)appearance of inverse emulsion particle by using JEM-100CXⅡtypeTEM.4、We had synthesized cation copolymer P (AM/DMDAAC) with monomers AM and DMDAAC, studied some effection factors as monomers molar ratio, initiator concentration, pH of polymerization system, types of emulsifier and their dosage to viscidity and stability capability of production, and confirmed the best synthesizetechnicscondition:w(AM)=40%;m(Span-80):m(Op-10)=96:4,w(Span-80+Op-10)=6.0%;n(DMDAAC):n(AM)=1.6;w((NH4)2S2O8)=1.0%;polymerization system pH=5.0; temperature 40℃;w((NH4)2S2O8): mass fraction ofammonium per sulfate in AM and DMDAAC; w(Span-80+Op-10): mass fraction of Span-80 and Op-10 in oil phase; product viscidity: 0.78Pa·s. We had also analyzed and characterized copolymer P (AM/DMDAAC) appearance of inverse emulsion particleby using JEM-100CXⅡtypeTEM.In conclusion, three polymers like PAM、P(AM/AANH4)、P (AM/DMDAAC) with some characteristics as high stability and apparent viscidity, solve rapidly in water were producted by Inverse Emulsion Polymerization. We expect broadly application inthese fields as water absorption resin, reclaim oil, flocculation, thickener, cation macromolecule flocculation and paper making, and so on.Keywords: Inverse Emulsion Polymerization; Dimethyldiallylammonium Chloride; Homopolymerition; Cationic Copolymerition; Thickener西北师范大学IV化学化工学院独创性声明 本人声明所呈交的论文是我个人在导师指导下进行的研究工作及 取得的研究成果。尽我所知，除了文中特别加以标注和致谢的地方外， 论文中不包括其他人已经发表或撰写过的研究成果，也不包含为获得 西北师范大学或其他教育机构的学位或证书而使用过的材料。与我一 同工作的同志对本研究所做的任何贡献均已在论文中作了明确的说明 并表示了谢意。 签名： 日期： 关于论文使用授权的说明 本人完全了解西北师范大学有关保留、使用学位论文的规定，即： 学校有权保留送交论文的复印件，允许论文被查阅和借阅；学校可以 公布论文的全部或部分内容，可