氧化铋掺杂对铌酸钾钠无铅压电陶瓷性能的影响.docVIP

------------------------------------------------------------------------------------------------——————————————————————————————————————氧化铋掺杂对铌酸钾钠无铅压电陶瓷性能的影响 第35卷第9期 第35卷第9期 2007年9月 赵 军等：梯度功能陶瓷圆球的抗热震性 · 1141 · Vol. 35，No. 9 September，2007 硅 酸 盐 学 报 JOURNAL OF THE CHINESE CERAMIC SOCIETY 刘代军，杜红亮，唐福生，罗 发，周万城 (西北工业大学，凝固技术国家重点实验室，西安 710072) 摘 要：用传统固相反应法制备了结构致密的铌酸铋钾钠[(Na0.5K0.5)1–3xBixNbO3，0≤x≤0.05]无铅压电陶瓷，研究了掺杂氧化铋(Bi2O3)对铌酸钾钠(Na0.5K0.5)NbO3 (NKN)晶体结构和压电性能的影响。结果表明：当Bi2O3含量xlt;0.02时，能得到具有纯钙钛矿结构的(Na0.5K0.5)1–3xBixNbO3陶瓷。最佳烧结温度随Bi2O3含量的增加而升高，与纯铌酸钾钠陶瓷相比，样品密度显著提高。Bi2O3掺杂量对铌酸钾钠的压电性能有很大影响，其压电常数(d33)，机电耦合系数(kp，kt)随Bi2O3含量的增加先升高而后降低，并在x=0.01时达到最大值，机械品质因数(Qm)有明显提高。实验表明：当x=0.01时，(Na0.5K0.5)1–3xBixNbO3无铅压电陶瓷的密度达4.42 g/cm3，表现出优异的压电性能：d33=154×10–6 C/N，kp=45%，kt=46%，介电损耗tanδ=3.5%，相对介电常数εr=598，Qm=138。 关键词：无铅压电陶瓷；铌酸钾钠；压电性能；氧化铋 中图分类号：TM282 文献标识码：A 文章编号：0454–5648(2007)09–1141–05 EFFECTS OF BISMUTH OXIDE-DOPING ON PROPERTIES OF POTASSIUM SODIUM NIOBATE LEAD-FREE PIEZOELECTRIC CERAMICS LIU Daijun，DU Hongliang，TANG Fusheng，LUO Fa，ZHOU Wancheng (State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi#39;an 710072, China) Abstract: Lead-free piezoelectric ceramics (Na0.5K0.5)1–3xBixNbO3(0≤x≤0.05) were synthesized by a traditional solid state reaction. Effects of bismuth oxide (Bi2O3)-doping on the crystal structure and piezoelectric properties of (Na0.5K0.5)NbO3 (NKN) were investi-gated. The results reveal that the pure perovskite structures of NKN-based ceramics were gained when the content of Bi2O3 content xlt;0.02. The optimum sintering temperature increases with the increase in content of Bi2O3, and the density of all samples are greater than that of pure NKN ceramics. Furthermore, the piezoelectric constant (d33), electromechanical planar and thickness coupling coef-ficients (kp, kt) increased firstly and decreased subsequently with the increase in content of Bi2O3. The mechanical quality factor