交流阻抗量测了解.pptVIP

* 耦合模型的應用 20(Li2O-Cs2O)-15Ga2O3-65GeO2 glasses Mixed alkali effect * The coupling model attributes the mixed alkali effect to mutual interception of jump paths of both kinds of mobile ions . Various experimental techniques have shown that there is a large local site energy difference between two different alkali ions in the mixed alkali glasses. Therefore, jumping of an alkali ion to the sites for a different alkali ion cannot occur. It follows that there are fewer sites for ionic motion of the host alkali species when different alkali ion is introduced. This will immobilize both different alkali ions. The immobilization effect can propagate to the second nearest neighbor host ions and beyond, resulting in a decrease of mobility of a large number of host ions and the decrease of conductivity of the sample. This blocking will reduce the number of effective mobile ions as well as increase the distance between mobile alkali ions. Hence, when different alkali ion is introduced, coupling interaction between mobile ions will be decreased. * Figure (c) shows a curve overlapping for samples Li8 at 360oC and Li20 at 150oC. The ion motion in the former sample is influenced most by the blocking effect, while there is no blocking effect for the latter one. According to the coupling model, sample influenced by the blocking effect has less effective mobile ions. Therefore, ions in sample Li8 need more thermal energy to have the same behavior as those in samples Li20 at low temperature. Also the width of the curve for Li8-360oC is narrower than that for Li20–150oC. This indicates that the coupling interaction between ions in the former one is smaller than that in the latter one. This is consistence with the blocking effect proposed in the coupling model. * ion–ion coupling is predominate ion–ion coupling and the ion and structural-relaxation are both important * The variation of n with lithium oxide fraction at nearly constantτ (2.5± 0.5× 10-5 s). The dashed curve is for eyes