镁铝双羟基水合物的合成及其对碘离子吸附性能的的研究.docVIP

PAGE 1 镁铝双羟基水合物的合成及其对碘离子吸附性能的研究 摘要 镁铝双羟基水合物(Magnesium Aluminate double hydroxyl hydrate，简写为Mg-Al-LDHs)，又称类水滑石化合物(Hydrotalcite like compound，简写为HTlc)，是一类由带正电荷层和层间填充带负电荷的阴离子所构成的阴离子型层状化合物，在吸附、离子交换和催化等领域具有广泛的应用。实验室以硫酸镁、硫酸铝、硝酸镁、硝酸铝、氢氧化钠及纯碱等为原料，采用共沉淀法制备了镁铝水滑石。并进行了IR光谱图表征，表征结果表明：镁铝水滑石结构中含有主要基团氢键、-OH、C-O。经过研究了镁铝水滑石对碘离子的吸附性能，研究表明，镁铝水滑石对碘离子具有较好的吸附性能。镁铝水滑石对水溶液中碘离子吸附的最佳条件为：碘离子初始浓度为100mg/L，投加量为3.5g/L，吸附温度为25℃，吸附时间为8h，吸附初始pH为7.5，其对碘离子的吸附符合Langmuir方程，饱和吸附量达22.32mg/g。通过对镁铝水滑石的动态吸附的研究得到：改变吸附剂高度,吸附剂高度越大,穿透时间越长。当吸附剂高度为5cm时，出水时间小于3h时，几乎可实现碘的零排放，在碘离子的初始浓度为200mg/L,pH=7.5,流速为4.5mL/min的条件下,此时处理的水量为810mL。动态吸附达到最大饱和吸附量为17.55mg/g。水滑石类材料与传统的吸附剂相比，具有吸附容量大、无毒无害、可再生等优点，是一种高效的吸附剂。研究得出了镁铝水滑石对碘离子吸附的部分理论数据和条件，为镁铝型水滑石的工业化应用提供了一些参考。 关键词：镁铝双羟基水合物,吸附,吸附等温线,穿透曲线 MAGNESIUM ALUMINATE DOUBLE HYDROXYL HYDRATE OF SYNTHESIS AND DISCUSSES IODINE ION ADSORPTION PERFORMANCE OF RESEARCH Abstract Magnesium Aluminate double hydroxyl hydrate(Magnesium Aluminate double hydroxyl hydrate,abbreviations for Mg-Al-LDHs),Also called Hydrotalcite like compound(Hydrotalcite like compound,abbreviations for HTlc),which is a kind of for by positively charged layer and layer is filled the negatively charged anion between constitute anion type layer compound,in adsorption,ion exchange and catalytic have been widely used.Through laboratory with magnesium sulfate,alumina,nitric acid magnesium,aluminum nitrate,sodium hydroxide and soda ash as raw material,adopting total precipitation preparation of Mg-Al-LDHs.And was confirmed by IR spectra characterization,characterization results show that magnesium aluminate hydrotalcite structure contains main groups hydrogen bonding,-OH,C-O.After the study of the magnesium aluminate hydrotalcite iodine ion adsorption performance.Research s