Eu3+,Bi3+共掺CaCO3红色荧光粉 材料性能研究.pdfVIP

Optoelectronics 光电子, 2015, 5(4), 49-56 Published Online December 2015 in Hans. /journal/oe /10.12677/oe.2015.54008 A Study of Luminescent Properties of CaCO3:Eu3+, Bi3+ Red Phosphors * Longyan Wu, Yun Li , Bo Yan, Chenghua Sui Science College, Zhejiang University of Technology, Hangzhou Zhejiang nd th th Received: Nov. 22 , 2015; accepted: Dec. 5 , 2015; published: Dec. 14 , 2015 Copyright © 2015 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract CaCO :Eu3+, Bi3+ are synthesized by the hydrothermal co-precipitation method. Under the ultra- 3 violet light excitation at 360nm, which is the excitation wavelength of Bi3+ but not of Eu3+, the typ- 3+ 3 ical emission peaks of Eu are observed. Considering that the excitation spectra of Eu + and the emission spectra of Bi3+ are partially overlapped, these results show that the luminescent effi- ciency of CaCO3 phosphors can be improved by the energy transfer from Bi3+ to Eu3+. The maximal emission peak of CaCO3:Eu3+, Bi3+ locates in the vicinity of 593 nm, corresponding to magnet- 5 7 3+ 3+ ic-dipole transition D → F of Eu , which confirms that the Eu ion locates in a high inversion 0 1 center. With the increase of the doping concentration of Eu3+, the relative light intensity of Eu3+ e