水溶性cdxzn1-xte三元量子点的制备 性能及应用-preparation and application of water-soluble cdx zn 1 - xte ternary quantum dots.docxVIP

等缺点，将对进一步反应得到的CdZnTe量子点的荧光性能产生影响。而一步法操作相对简单，重复性好，并且通过调节实验参数后得到的CdZnTe量子点其量子效率在480～590nm波长范围内均可达到50%以上，高于目前水溶性量子点的文献报道结果。此外，由于GSH是一种广泛存在于人体的解毒剂，其与重金属离子之间存在很强的螯合作用，因此当GSH稳定的量子点溶液中存在重金属离子时，GSH与重金属离子的结合将引起量子点表面状态的变化，从而引起其荧光性能的变化。所以，我们将制备得到的GSH-CdZnTe三元量子点应用于铅、汞离子检测中，研究了不同CdZnTe量子点浓度以及不同铅、汞离子浓度时，量子点的荧光强度衰减程度。结果表明，当样品溶液中CdZnTe量子点的浓度为0.5μM、铅离子浓度为10nM时，其荧光强度衰减幅度可达22%。而当CdZnTe量子点的浓度为0.5μM、汞离子浓度为25nM时，其荧光强度衰减幅度可达20%，有力的说明了GSH-CdZnTe三元量子点在离子检测方面具有良好的应用前景。关键词：三元量子点，CdZnTe，水溶性，半导体纳米颗粒，离子检测AQUEOUSSYNTHESIS,CHARACTERIZATIONANDAPPLICATIONOFCdxZn1-xTeALLOYEDQUANTUMDOTSABSTRACTSemiconductornano-crystalsorquantumdots(QDs)haveshowntheirtremendouspotentialforapplicationsinbiomedicalareasespeciallyinbiomedicallabeling,fluorescentbio-probeandsoon.Water-basedpreparationofQDshasbecomeoneofthemostattractivepointsbecauseoftherequirementoftheirapplicationsinbiomedicalareas.Recently,synthesisofbinaryQDsorcore-shellstructuredQDsinaqueoussolutionhasachievedgreatprogresswhilethesynthesisofwater-solublealloyedQDsstillhasitslimitation.Moreover,alloyedQDspreparedthroughaqueousroutemostlyhavetunableemissionwavelengthwithinblueornear-infraredrange,whichlackofcounterpartswithbothhighphotoluminescencequantumyield(PLQY)andvisible-light-emittingspectra.Inthispaper,bothtwo-stepprocessandone-stepprocesssyntheticmethodswereusedtopreparewater-solubleCdZnTealloyedQDswithglutathione(GSH)asstabilizer.Asforthetwo-stepprocessmethod,ZnTenanocrystalseedswerepreparedfirstly,andthenCdprecursorwasaddedtosynthesizeCdZnTealloyedQDs.However,intheone-stepprocessmethod,Cd,Zn,andTeprecursorsweremixedsimultaneouslytosynthesizeCdZnTealloyedQDs.Withthesetwomethods,GSH-CdZnTealloyedQDswithfluorescentemissionwavelengthrangefrom470to605nmcouldbeobtained,andtheirQYscouldreachupto75%.Furthermore,wesystemicallyinvestigatedtheinfluencesofreactiontime,molarratioofprecursorandpHvalueonthefluorescentpropertiesofCdZnTeQDs.Accordingtotheresults,drawbackssuchasinconvenientexperimentalprocedureorpoorreproducibilityinthetwo-stepprocesslimitedt