水热老化及硫化对zrti改性的pdceo2催化剂性能的影响-effect of hydrothermal aging and sulfidation on the performance of zrti modified pd ceo 2 catalyst.docxVIP

目录前言..............................................................................................................................................1第一章文献综述.............................................................................................................................11.1研究背景............................................................................................................................11.1.1柴油车特点及尾气组成.........................................................................................11.1.2柴油车尾气排放相关标准及尾气净化技术.........................................................31.1.3柴油车尾气净化.....................................................................................................41.2柴油车氧化催化剂(DOC)6DOC的作用及组成6DOC的发展历程71.3贵金属DOC81.3.1贵金属DOC的催化氧化性能81.3.2Pd基负载型催化剂91.3.3Pd/CeO2催化剂的催化氧化101.3.4Pd/CeO2存在的问题及改进11Pd/CeO2抗硫性能改进12Pd/CeO2热老化性能改进131.4研究目的和意义..............................................................................................................14第二章实验部分...........................................................................................................................152.1样品制备..........................................................................................................................152.1.1原料及实验仪器...................................................................................................152.1.2样品制备过程.......................................................................................................载体制备过程............................................................................................新鲜及老化催化剂样品制备过程............................................................硫化样品制备过程....................................................................................172.2活性测试..........................................................................................................................172.2.1评价气氛...............................................................................................................172.