生物塑料聚3-羟基-co-4-羟基丁酸酯p34hb及聚己二酸对苯二甲酸丁二酯pbat对聚乳酸pla性能改进研究-study on the performance improvement of poly ( 3 - hydroxy - co - 4 - hydroxybutyrate ) p34hb and poly ( butylene adipate ) terephthalate pbat on pla.docxVIP

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2018-08-01 发布于上海
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生物塑料聚3-羟基-co-4-羟基丁酸酯p34hb及聚己二酸对苯二甲酸丁二酯pbat对聚乳酸pla性能改进研究-study on the performance improvement of poly ( 3 - hydroxy - co - 4 - hydroxybutyrate ) p34hb and poly ( butylene adipate ) terephthalate pbat on pla.docx

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生物塑料聚3-羟基-co-4-羟基丁酸酯p34hb及聚己二酸对苯二甲酸丁二酯pbat对聚乳酸pla性能改进研究-study on the performance improvement of poly ( 3 - hydroxy - co - 4 - hydroxybutyrate ) p34hb and poly ( butylene adipate ) terephthalate pbat on pla

AbstractThermoplasticpolymerpolylacticacid(PLA)isakindofcompletelybiodegradableplastics,thehightensilestrengthandmodulusofelasticitymakesthePLAhasreceivedthewidespreadattention.Buttheshortcomingssuchasthebrittlenessandtheslowcrystallizationrateseverelyhamperitsdevelopmentandpracticalapplication.InordertoimprovethecrystallizationrateandshockresistanceofPLA,thispaperchoosetwokindsoffullybiodegradablematerial:poly(3-hydroxybutyrate-co-4-hydroxybutyrate)(P3/4HB)andpoly(butylenesadipate-co-terephthalate)(PBAT)toblendwithPLA.InPLA/P3/4HBblend,withtheincreaseof4HBunit,P3/4HBhasdifferenteffectsonthePLAproperties:themodificationeffectofthesemi-crystallizationplasticsofP(3HB-co-5%-4HB)andP(3HB-co-10%-4HB)onPLAisweaker,thetransitionstateofP(3HB-co-20-%4HB)possessthebestmodificationabilityamongfiveP3/4HBmaterials,thePLA/P(3HB-co-20%-4HB)blendcomprehensiveperformanceisgoodwhenP(3HB-co-20-%4HB)was20wt%,withthetensilestrengthof38.18MPa,Young’smodulusof2.71GPa,elongationatbreakof51.82%andthenotchedimpactstrengthof30.92KJ/m2.AmorphouselastomersofP(3HB-co-27%-4HB)andP(3HB-co-32.4%-4HB)improvethecrystallizationpropertiesofPLA,experimentalresultsshowedthattheP(3HB-co-32.4%-4HB)coulddecreasethecrystallizationhalftimeofPLAfrom26.53minto5.92minwhenisothermalcrystallizationtemperaturewas100℃,andthesurfacefreeenergyofcrystaldecreasedfrom56.25ergcm2to36.68erg/cm2.ThenanoscopicvoidsemergedonthecrosssectionofalltheblendscarriedoutbySEM,theporesizewasrelatedwiththe4HBcontent,0.013μm2averageareaand18.7%superficialareaoccupancyofthenanoscopicwascalculatedwhenP(3HB-co-32.4-%4HB)was20wt%.Poly(butylenesadipate-co-terephthalate)(PBAT)isabiodegradablealiphatic–aromaticcopolyesterwithhightoughnesssynthesizedfromadipicacid,terephthalicacidandbutyleneglycol.Usingdicumylperoxide(DCP)asacrosslinkingagenttomodifytheconsistencyofPLAandPBAT.AlsoexaminescombinationpropertyofPLA/P(3HB-co-24%-4HB)blendingwiththePBAT.MechanicalpropertiesexperimentalresultsshowthatPBATcanimprovethenotchedimpactstrengthandelongatio