石墨烯对水中溶解油的吸附性能分析-analysis on adsorption performance of graphene for dissolved oil in water.docxVIP

graphenestudiedinthisworkhasmuchbiggeradsorptioncapacity.TheadsorptionofdissolvedoilinwaterwasnotaffectedbypH,indicatingthiskindofmaterialhavegoodacidandalkaliresistance.Whenthesalinitywasbetween2.0%and3.5%,theadsorptioncapacityincreasedwiththesalinityincrease,butitdecreasedwhenthesalinitywasbetween3.5%and4.0%.inaddition,Theadsorptioncapacityincreasedwiththetemperaturerise.Finally,adsorptionmechanismwasproposedbycombiningadsorptionkineticwiththermodynamicexperiments,weassumedthatthelargesurfaceareaandthehighsurfacehydrophobicityofgrapheneenabledastrongadsorptionaffinityandcapacityforsolubleoil.Furthermore,thegraphenehoneycomblatticewascomposedoftwoequivalentsub-latticesofcarbonatomsbondedtogetherwithσbonds,andeachcarbonatominthelatticehadaπorbitalthatcontributedtoadelocalizednetworkofelectrons.Thereforesolubleoilwasadsorbedongraphenebyπ-πstackinginteractions.becauseofitslow-molecular-weightPAHs.KEYWORDS：Graphene,Dissolvedoil,Contactangle,AdsorptionmechanismIV目录第一章文献综述.............................................................................................................................11.1石油的组成........................................................................................................................21.2海洋石油污染....................................................................................................................21.3海洋石油污染的危害........................................................................................................41.4水中溶解油的形成及其毒性作用的原理........................................................................51.4.1石油在海洋的迁移与转化.....................................................................................51.4.2水中溶解油的形成.................................................................................................61.4.3水中溶解油的毒性效应.........................................................................................61.5溢油事故的处理方法.................................................................................................