热浸镀锌铝的界面反应及熔池的热力学分析-interfacial reaction of hot-dip galvanized aluminum and thermodynamic analysis of molten pool.docx

成，将导致熔池液相直接接触钢基而发生界面反应控制的反应过程，镀层金属间化合物层的厚度将显著增厚。在锌铝熔池中添加铜能有效的抑制其铁铝之间的反应，铜的加入能促使τ5的形成，同时控制Fe2Al5层的快速增厚。当0.5~1.0wt.%的铜加入到锌铝熔池时，铜能够促使硅在界面反应区域富集，该区域之前熔池液相与FeAl3相的平衡被液相与τ5之间的平衡关系所取代，此时界面反应扩散通道为(钢基/Fe2Al5/FeAl3/τ5/锌铝熔池)，镀层金属间化合物外层形成致密的τ5相层，这种现象避免了熔池液相直接腐蚀钢基，从而控制了钢基与熔池之间的反应，镀层的金属间化合物层厚度明显减薄，Fe2Al5相层减薄程度尤为明显。试验研究了硅含量在1.0～3.0wt.%范围内，温度580～610°C时熔池中锌铝渣相的形成机理，熔池中所形成的锌铝渣相被鉴别为FeAl3相和含锌的τ5相。同时在580～610°C温度范围内建立了Zn-Fe-Al–Si四元体系中(Al0.55Zn0.45)1-x-yFexSiy截面富锌铝侧相平衡关系，可以直观的看出随熔池硅含量和温度的变化，熔池中所含锌铝渣的种类。当硅含量不超过1.3at.%时，熔池中锌铝渣相仅为FeAl3相，在1.0～1.6wt.%硅含量锌铝池中所形成的FeAl3相中最大的硅含量为1.93wt.%。当硅含量达到2.0wt.%时，熔池中仅含有τ5锌铝渣相。在本研究工作中，580～610°C温度范围内1.6wt.%硅含量熔池中均出现FeAl3相和τ5相共存的现象。关键词:热浸镀锌铝；界面反应；锌铝渣；Zn-Fe-Cu；Zn-Al-NiAbstractHotdipgalvanizingiswidelyusedtoimprovetheatmosphericcorrosionresistanceofthesteelsheet.Thecorrosionresistanceofthehot-dippingZn-Alcoating(forexampleZn-55%Al,Zn-5%Alcoatingetal.)issuperiortoasinglecoating(Zn,Alcoating).Becauseofthepresenceofaluminum,resultinginthestrongandrapidexothermicreactionbetweenthesteelmatrixandtheA1-Znbath,rapidgrowthofalloylayer,andlargeamountsofZn-Aldrossforminginthebath.Tocontroltheviolentreactionoccursbetweentheironsubstrateandbath,thealloyingelements,suchasSiandCu,willbeaddedintheA1-Znbath.FocusingontheinteractionbetweenFe,Zn,AlandSi,therelatedphasediagramsweredeterminedandtheeffectofalloyingelementsoncoatingswerecarriedout.Theinterfacialreactionandformingofintermetallicdrossphasesinhot-dippingZn-Albathhavebeenstudied,whichisimportanttocontrolthemicrostructureofZn-Alcoating.The450°C、620°Cand800°CisothermalsectionoftheZn-Fe-Cuternarysystemwasexperimentallydetermined.Nonewternarycompoundwasfoundinthesystem.Eightthree-phaseregionsexistinthe450°Cisothermalsection.isothermalsection.ExperimentalresultsindicatedthatthesolubilityofCuintheΓ(Fe3Zn10)andtheδFephasereachesashighas17.9at.%and15.2at.%,respectively,andthesolubilityofCuinliquidandζphaseislower.Theresultsconfirm,ingalvanizing,theadditionofCuinbathupto1.0at.%wouldfavortheformationoftheΓphaseandδFephases,theotherw