系列金属复合氧化物的合成及对染料光催化性能的分析-synthesis of a series of metal complex oxides and analysis of their photocatalytic properties for dyes.docxVIP

ABSTRACTPerovskite-typeoxides(FeYO3,SrFeO3,YCrO3,LaCrO3,CaZrO3,SrZrO3,BaZrO3),scheelite-typeoxides(CaCrO4,SrCrO4,BaCrO4)andspinel-typecompositeoxides(BaFe2O4)weresynthesizedbySol-gelmethodusingcitricacidasthecomplexingagent.Thedifferentreactionconditionssuchassinteringtemperature,sinteringatmosphere,thepressureofreactionwereexploredbychemicalmethodsIRandTG.ThesamplesweredetectedbymeansofX-raypowderdiffraction(XRD),transmissionelectronmicroscopy(TEM),scanningelectronmicroscopy(SEM)andX-rayphotoelectronspectrometry(XPS)inordertocharacterizethestructure,surfacemorphology,internalparticlediameterandthesurfaceoxygencontentofthesamples.Theresultsshowedthatmetalcomplexoxideswithsingle-phasestructurecanbesynthesizedbySol-gelmethod.TheaverageparticlediametersofmostsampleswerecalculatedbytheDebye-Scherrerformulawhichweresmallerthan100nm.Sothesamplesbelongtonamoparticle.Thecitratesol-gelmethodhassomanyadvantagessuchassimpletechnology,shortreactiontime,highpuritysyntheticproducts,easiertoindustrializedproduction.Hence,thismethodhasbroadprospectofdevelopmentandapplication.Thisarticlefocusesondyewastewaterphotocatalyticdegradationtestusingtheperovskite-typecompositeoxidesasphoto-catalysts.Andthatthereasonofphotocatalyticdegradationofdyes,illuminationtime,diversecatalystswerealsoexploredinthisarticle.Photocatalyticdegradationexperimentsofsolubleacidic,alkaline,neutral,andamixtureofallthreedyetestsweredoneusingACrO3(A=Y,La)andAZrO3(A=Ca,Sr,Ba)asphoto-catalysts.AndwecangettheimpactoftheA-siteionsofthecompositeoxidetothephotocatalyticdegradationefficiency.ThefinalanalysisfromtheperspectiveofthenegativepowerandtolerancefactorobtainedshowedthatthesmallertheionicradiusoftheAbit,thehigherefficiencyofphotocatalyticdegradationwhenthecompositeoxideABO3withthesameionB.Butitalsochangedbythecontentofthesurfaceoxygenspecies.Itcanbesummedupbyphotocatalyticexperimentsthatthephotocatalyticefficiencyofcompositeoxidespreparedbycitratesol-gelmethodisveryhigh,andithasboththeoreticalsignificanceandprac