烷胺盐和乳酸金属配合物的晶体结构及热化学分析-crystal structure and thermochemical analysis of metal complexes of alkylamine salt and lactic acid.docx

聊城 聊城大学硕士学位论文 ii ii ABSTRACT In recent years, phase change materials have caused extensive concern in the field of energy utilization and material science. Phase change energy storage technology can solve the contradiction of energy supply and demand in time and spatial. Therefore it is an effective way to improve energy utilization. The developed countries in which energy storage technology application has been relatively mature, have invested heavily in the development of new energy storage technology and energy storage materials, expecting these materials to be technical, economical and reliant. Our country has carried out active research and made great achievements in this field. Carbohydrate can provide energy and carbon for organisms. The monosaccharides often contain 3-6 carbon atoms in nature. There are many kinds of monosaccharides acid in organisms, such as glucose acid, ribonucleic acid and lactic acid. Thess monosaccharides have their physiological functions and nutritional value in organism respectively. We have found by the experimental study and clinical application that complexes of monosaccharide acids combinding metal elements have even more significant physiological activity and nutritional value for the organisms. In order to explore the complex, we need accurate thermodynamic data for the industrial alapplication and related theoretical research. In this paper, main works of this thesis are as follows: Twelve kinds of phase change materials and ten kinds of lactates were synthesized respectively. The compositions and spatial structures of the complexes were characterized by element analysis and X-ray single crystal diffraction technique. The lattice potential energies were calculated based on the crystal data. According to Pitzers electrolyte solution theory, the molar solution enthalpy of lactates which are very soluble in water at infinite dilution ( ??H ??) and Pitzers s m parameters were obtained at 298.18 K. Thermal anomaly i