铁基纳米吸附剂烟气脱汞实验及机理分析-experiment and mechanism analysis of mercury removal from flue gas by iron-based nano adsorbent.docx

华中科技大学博士学位论文 华 中 科 技 大 学 博 士 学 位 论 文 IV IV addition the efficiency is obviously higher. The inhibiting effect of SO2 on Hg capture was detected which could compete for adsorption sites with mercury. The inhibitory effect is proportional to SO2 concentration. The catalytic characteristic of nano-Fe2O3 for elemental mercury especially the effects of particle size of nano-Fe2O3, reaction temperature, crystalline phase and flue gas components on the catalytic removal of mercury were studied. From the oxidation test results, it was founded that the decrease of the power size, as well as the increase of temperature could enhance elemental mercury oxidation, while exorbitant temperature could result in sintering, which could destroy the pore structure and damage the activity. The difference of crystal structure between α-Fe2O3 and γ-Fe2O3 nanoparticles plays a prominent role in mercury oxidation. Due to the oxygen in the γ-Fe2O3 has higher thermodynamic chemical potential and activity than α-Fe2O3, γ-Fe2O3 nanoparticles show much higher activity for mercury catalytic oxidation and more sensitive to condition changes. The presence of oxygen is the basis for catalytic reaction .The presence of water vapour shows different effect on mercury oxidation depending on its concentration. The lower content of water vapour can promote mercury oxidation slightly, which results from the hydroxyl produced on the surface of nano samples. while the higher content of water vapour inhibits mercury oxidation. The addition of NO, NO2, SO2 and HCl could enhance the mercury oxidation with the tendency HCl NO2 SO2 NO; to the effect of combination of acid gas, the highest oxidation efficiency was achieved under NO2 + HCl condition. The sol-gel process was used for the process of Fe2O3/SiO2 nanocomposites preparation with citric acid as active agent. And the process was optimized with orthogonal experimental method. The experiments of element mercury removal using Fe2O3/SiO2 nanocompo