The catalyst of environmental catalysis (英语论文).docVIP

The catalyst of environmental catalysis Molecular chemisorption at manganese oxide/liquid interfaces has attracted increased interest due to its importance in the development of heterogeneous catalysts, microbial fuel cells and selective adsorption. Recently, inexpensive manganese oxide based catalysts instead of noble metal catalysts have been investigated in the catalytic wet oxidation (CWO) of phenolic wastewater. However, the adsorption of organic compounds on manganese oxide surfaces, which plays an important role in electron transfer and oxygen reduction, has not fully been explored. Phenol has attracted more attention in wastewater treatment because of its toxicity and wide occurrence in wastewater. Several conversion processes, currently under development for the production of synthetic fuel from coal, discharge substantial amounts of phenol (0.2-0.5g/L). Moreover, phenol is taken as a model compound for the study of adsorption and oxidation because phenol is an intermediate product in the oxidation of higher-molecular-weight aromatic compounds and phenol also converts to a series of intermediates on oxidation. Cryptomelane-type manganese oxide is an octahedral molecular sieve (OMS) composed of 2x2 edge-shared Mn06 octahedral chains, which are corner shared to form onedimensional tunnels. Potassium ions and water are located in the tunnels (designated K-OMS-2). Mixed-valent manganese ions (Mn2+ and Mn3+) are situated in the octahedral sites of cryptomelane. Transition metal ions can be incorporated into the framework or tunnel sites. Sizes and charges of M determine which sites are occupied. The synthetic counterpart of metal ion doped cryptomelane is known asoctahedral molecular sieve M-K-OMS-2 (M doped metalions). In recent years, some work has been published on the syntheses of cryptomelane-type manganese oxides and their applications in the oxidation of benzene, carbon monoxide, and other hydrocarbons. K-OMS-2 was found to possess excellent hydrophob