铁氧体纳米粉体的合成 表征及性能分析-synthesis, characterization and performance analysis of ferrite nanopowders.docxVIP

共沉淀法合成的产物为纳米颗粒，直径大小约为50nm。另外，分别研究了不同方法的不同条件下合成的产物对MB与CR的吸附性能，发现不同方法的产物对不同的染料有选择吸附性，且具有磁性可回收性能。5、采用共沉淀法制备了纳米粉体BiYO3可见光光催化剂，并在可见光下催化降解罗丹明B（RhB）与甲基橙染料(MO)水溶液，研究了不同沉淀剂、焙烧温度对BiYO3的结构及光催化活性的影响。结果表明：在双氧水的协同作用下，以氨水为沉淀剂在500℃条件下焙烧合成的BiYO3光催化活性较高。另外，将四种沉淀剂的产物进行了吸附性能测试，发现四种吸附剂对3种阳离子染料吸附能力较弱，但对刚果红阴离子染料的吸附效率很高。其中，碳酸根离子团沉淀剂的产物吸附效率高于氢氧根离子团沉淀剂的产物的。关键字：铁氧体，盐助溶液燃烧法，溶胶凝胶法，共沉淀法，光催化，吸附AbstractInrecentyears,dealingwithwaterpollutionisoneofthehotspotofenvironmentalstudies,thephotocatalyticdegradationandadsorptionarebothconsideredtobeeffectivemensofgreenmanagement.Bisides,ferritecompositeoxideshavewidelyusedinvariousfieldsbecauseofitsexcellentferromagnetism.Therefore,ferritematerialswithmagneticwerepreparedbythemethodwhichwassimple,convenientandquickinourpresentwork,anditisofgreatimportencetoappliedittodealwiththewaterpollution.Single-crystallineYFeO3particleswiththeperovskitestructurehavebeenfabricatedthroughafacileKCl-assistedsolutioncombustionsynthesis(SSCS)route,usingalanineasfuelandcorrespondingnitratesasoxidants.TheeffectsofF/NandtheKCl/MratiosonthephaseandmicrostructureoftheproductsarestudiedindetailbyXRDanalysis,SEM,lowtemperatureN2adsorption,UV?visiblediffusereflectionspectroscopy.ItisremarkablethattheintroductionofKClintothesolutioncombustionsynthesis(SCS)processresultsinadramaticincreaseinsurfaceoftheobtainedYFeO3.ResultsshowthatbothofYFeO3nanoparticlespreparedbySCSandSSCSexhibitexcellentphotocatalyticactivityforthephotodegradationofRhBinthepresenceofH2O2.Thephotogeneratedholes(h+)and?OHwerethemainactivespeciesofYFeO3forRhBdegradationundervisiblelightirradiation.DifferentcrystallinephasesYFeO3nanopowderssynthesisedviasol-gelmethodusingeggwhiteasthecomplexingagent.Byadjustingthepreparationparametersinthesynthesisprocess,whichdemonstratedthattheamountofcomplexingagent,calciningtemperatureandtimehaveimportantinfluenceonthecrystallinephaseandadsorptiveabilityofYFeO3.Therein,thestructureofhexagonalYFeO3wasmesporous,anditsaverageporesizewas21.3nm.Furthermore,theadsorptionpropertiesofYF