碳纤维前驱体熔纺聚合物的制备与性能分析-preparation and property analysis of melt spun polymer of carbon fiber precursor.docxVIP

最后将所得聚合 产物溶解在二 甲基甲wt肢(DMF)中，用静电纺丝法进行纺丝 ， 探讨静 电纺丝工艺和l聚合物的可纺 性。结果表明，在聚合物浓度为 8 lO %.施加 电压为 15 千伏肘 ，可得到聚丙烯脂纤维毡 。 关键词: 聚丙烯脂:聚合工艺;烙融:静电纺丝 Study 00 Preparatioo aod Properties of Melt-spiooin g polymer precursors for Prepariog carboo fibers Subject: Materials Science Name: Peng su-yun Supervisor: Professor Zhan g wan g-xi Abstract This paper makes the comonomers copolymer with acrylonitrile，changes the thenn al properties of PAN by ch anging the composition and structure，so that polyacrylonitri le can be melt. This paper have three parts: (1) copolymerization of acry lonitrile (AN)，methy l acry late (1队)and acry lic acid (AA) ; (2) copoly merization ofacηllonitri le (AN) and methyl acry late ⑦t1A); (3) electrospinn ing of copolymer. The copoly merization of AN 、 MA and AA is carri ed Ollt in water，lIsing potassi llm persulfate (K SP) and sodium bisulfite (SBS) as the initiator to explore the effect of monomer ratio，react ion temperatUl毡，monom er con cen tration and initiator concentration on the polymeriza tion reaction. Because it is triple response，and AA will affect the PH of system ，so that discussin g the affection of monomer ratio is very complicated. Under certain conditions，with the increasing of monomer concentration and initiator concentration ，conversion rate wOllld reach a higher level in a short time，so both of th em can be not too high ，so as to avoid of inseclllity .Reaction tempe rature h as an important impact in the poly merization reaction . The reaction is too violent to safe at 60.C ; the temperature is too low to react below 40 .C The copolymeriza tion of AN and MA is carried out in water or the mixture of dimethy l fonn ami de and water ρ沁1F1H20)，using pot assillm persulfate (KSP) and sodium bisulfite (SBS) as the initiator，using isopropanol as chain transfer agent，to invest the effect of monomer ratio，react ion tempera 阳此，monomer concentrahon ，1I11hator concentration ，reaction medium and chain transfer agen t on the poly m eriz