铜蛋白的直接电化学及其电催化传感的分析-direct electrochemistry of copper protein and analysis of its electrocatalysis sensing.docxVIP

II II 明 Hc 的 Cu(II)/Cu(I)电对发生了氧化还原反应。双酚 A 在 Hc/CB/IL 复合膜中实 现了良好的电催化氧化，其峰电流与双酚 A 的浓度在 0.085 μM - 38 μM 范围内呈 现出良好的线性关系，检出限为 0.037 μM(3σ)。 关键词：铜蛋白；血蓝蛋白；二胺氧化酶；直接电化学；生物传感器 III III Abstract Cuprein widely exists in living organisms. It has a variety of physiological functions, such as oxygen carrier, electron transfer and oxidant, etc. Hemocyanin (Hc) and diamine oxidase (DAO) are all copper containing proteins. Hc is one of the three respiratory proteins in animal kingdom. It is a multi-functional protein acting as oxygen carrier, adjustment of the osmotic pressure in animal body, storage of the en