稀土掺杂nagdf4纳米晶上转换荧光及热效应分析-upconversion fluorescence and thermal effect analysis of rare earth doped na gdf 4 nanocrystals.docxVIP

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稀土掺杂nagdf4纳米晶上转换荧光及热效应分析-upconversion fluorescence and thermal effect analysis of rare earth doped na gdf 4 nanocrystals.docx

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稀土掺杂nagdf4纳米晶上转换荧光及热效应分析-upconversion fluorescence and thermal effect analysis of rare earth doped na gdf 4 nanocrystals

Abstract Because of excellent magnetic and optical properties, compounds containing Gd3+ have great potential in various fields. In addition, NaGdF4 also become hot spot topic in biomedical applications. In recent years, people have done a lot of works in the compound multi-functional materials of up-conversion fluorescence and Magnatic Resonance Imaging (MRI), there was a lot of reports and consequently realized the fluorescence detection and MRI analysis in organism. This thesis reports associated related further research in the up-conversion fluorescence of the rare earth co-doped NaGdF4,and an interesting finding on the property of NaGdF4. First, we investigated the influence of annealing temperature to the fluorescence intensity of hexagonal phase NaGdF4:Yb3+/Er3+, and then optimized the annealing temperature. We prepared the NaGdF4:Yb3+/Er3+ precursor with precipitation，and annealed them at 400 ℃-800 ℃. From the fluorescence spectrum measurements of the samples, we got the strongest intensity in the samples sintered at 600 ℃.And then we performed through the X Ray diffraction(XRD)、X Ray Fluorescence(XRF), experiments, we analysed the influence of oxygen ion doped by hyperthermia sintering on the crystal structure and the up-conversion fluorescence intensity of sample. Second, we measured the fluorescence intensity ratio of two green light in along with the change of the temperature, obtained the expression of FIR variation with temperature; And research the similar saturation phenomenon of NaGdF4: Yb3+/Er3+ samples sintered in 600 ℃. It was found the intension that gradually become flat in along with growing of laser power. And we gave an explanation to the thermal effect of samples induced by infrared laser that weaken or made quenches the fluorescent. And design two groups of experiments verify the explanation, the first group dispersed in the water, and powder and tabletting samples in the air, the second group is different concentrations of Yb3