原料对液固燃烧法合成尖晶石型LiMn2O4影响.docVIP

原料对液固燃烧法合成尖晶石型LiMn2O4影响 　　摘要: 以晶体醋酸锂或尿素为反应体系的液相，研究了不同锂和锰为原料，液－固燃烧合成制备尖晶石型LiMn?2O?4的影响.实验结果表明，不同锂和锰为原料对液－固燃烧合成LiMn?2O?4的影响较大，其中醋酸锂和二氧化锰为原料，可得到单相的尖晶石型LiMn?2O?4的产物，但加入尿素不利于合成LiMn?2O?4；以碳酸锂和二氧化锰或碳酸锂和碳酸锰为原料，产物中都有杂质，但碳酸锂和二氧化锰为原料优于碳酸锂和碳酸锰为反应原料. 　　? 　　关键词: 液-固燃烧合成；尖晶石型；锂离子电池；正极材料；LiMn?2O?4? 　　中图分类号:O 611；TM 911 文献标志码:A 文章编号:1672-8513(2011)05-0337-03 　　?? 　　 　　Effect of Different Raw Materials on Liquid-Solid ? 　　Combustion Synthesis of Spinel LiMn?2O?4 　　 　　GUO Jun?ming，HUANG Mei，XIA Yan，WANG Rui，BAI Hong?li 　　? 　　 　　 (Key Lab of Ethnic Medicine Resource Chemistry, State Ethnic Affairs Commission ? 　　 Ministry of Education，Yunnan University of Nationalities, Kunming 650500，China) 　　 　　Abstract: The effect of different raw materials on liquid-solid combustion synthesis of LiMn?2O?4 was investigated by using lithium acetate or urea as the liquid phase of the reaction system. The results indicated that the phase formation of liquid-solid combustion synthesized LiMn?2O?4 is affected greatly by different Li, Mn sources as raw materials; it obtained the single phase of Spinel LiMn?2O?4 when the raw materials were the lithium acetate and manganese dioxide, but the added urea was not beneficial to synthesize LiMn?2O?4. There are some impurities in the product when using lithium acetate and manganese dioxide or lithium acetate and manganese acetate as starting materials, but the starting materials by lithium acetate and manganese dioxide was superior to the reactants by lithium acetate and manganese acetate. 　　? 　　Key words: 　　liquid-solid combustion synthesis; spinel; Li-ion battery; cathode materials；LiMn?2O?4 　　 　　尖晶石型LiMn?2O?4是人们认为非常有希望的锂离子正极材料，其具有资源丰富、价格低廉、耐过充过放、无毒等特点，属环境友好型材料［1］.制备LiMn?2O?4的常用方法主要为传统固相法、共沉淀法、熔盐法、溶胶-凝胶法、液相燃烧法等［2-7］.? 　　根据液相燃烧合成和固相合成法的特点与优点，本文提出一种合成LiMn?2O?4物质的新方法――液-固燃烧合成.研究了以晶体醋酸锂或有机燃料形成液相，不同原料固体对液－固燃烧合成LiMn?2O?4的影响.? 　　1 实验方法? 　　以醋酸锂(70?℃)、醋酸锰(80?℃)、二氧化锰、碳酸锂、碳酸锰为原料，低熔点尿素（132.7?℃）形成燃烧反应体系液相，采用液－固燃烧合成方法制备尖晶型LiMn?2O?4.配料按物质的量比?n?（Li）∶?n?