吉林大学物理学05第五章.pptVIP

于是: 解得: x = 5.46?10-3 故: p(CO2) = x atm = 5.46?10-3atm ?101325Pa?atm-1 =553Pa p(NH3) = (0.1228+2x) atm = 0.1337?101325Pa=13550Pa p = p(NH3) + p(CO2)=14103Pa 例5.2.1 已知: T1=297.0K时 p(NO)=24136Pa m(Br2)=0.7040g T2=323.7K p(总)=30823Pa V =1.0547dm3 反应 2NOBr(g) = 2NO(g)+Br2(g) 的K? 求: 解: 323.7K时NO和Br2的原始分压为 p0(NO)=24136?(323.7/297.0)Pa =26306Pa p0(Br2)= 设平衡时NOBr的分压为xPa 平衡pB/Pa 2NOBr(g) = 2NO(g)+Br2(g) 原始pB/Pa 0 26306 11241 x 26306-x 11241-x p(总)=(x+26306-x+11241-x)Pa=30823Pa ?平衡分压p(NOBr) = xPa =13448Pa 因此 = 0.04