过渡金属基MOFs的合成及其衍生物的电化学应用本科毕业设计论文.docx

本科毕业设计（论文） 题目:过渡金属基MOFs的合成及其衍生物的电化学应用 专业班级:材料物理 13-1班 指导教师:胡松青 摘 要 由于人类对煤、石油、天然气等化石燃料的过度依赖，带来了一系列的环境问题，因此清洁、可再生的氢能源得制备成为近年来的研究热点。如今，电解水制氢（Hydrogen Evolution Reaction，简称HER）被认为是一种最理想的清洁制氢技术。如何降低电解水制氢的电位差是整个过程的核心内容，而催化剂的合理选择可以有效的降低电位差。MOFs由于具有较大的比表面积和高分散的活性位点，从而在电催化领域表现出了很大的潜力。一方面，我们选取了具有较大比表面积的MOF-71-Co作为前驱体，通过在不同条件下热解，合成了不同的纳米氧化物材料，通过对比发现，在氮气条件下400°C煅烧得到的氧化亚钴（CoO）电催化活性最高，不仅展现了优异的电催化析氧性能，还表现出一定的电催化析氢性能。另一方面，通过掺杂镍元素，来探究不同镍、钴比例对电催化活性的影响，发现原Co-MOF电催化活性最高。此外，运用TG、XRD、SEM等对其进行了基本表征，运用电化学工作站测试了其HER和OER性能。 关键词: 金属-有机框架物；MOF-71-Co；电催化析氧；电催化析氢  Synthesis of Transition Metal MOFs and Electrochemical Applications of Their Derivatives Abstract Human’s dependence on coal, oil, natural gas and other fossil fuels, brought a series of environmental problems, so seeking a clean,and renewable hydrogen energy has became a hot topic in recent years. Today, Hydrogen Evolution Reaction (referred to HER) is considered as an ideal cleaning hydrogen technology. How to reduce the electrolysis potential difference of water spitting is the core of the entire process, and the rational choice of the catalyst can effectively reduce the potential difference. MOFs have a great potential in the field of electrocatalysis due to their large specific surface area and highly dispersed active sites. On the one hand, we selected MOF-71-Co as a precursor with a large specific surface area, then, different nano-oxide materials were synthesized by different pyrolysis under different conditions. In the end,we found the electrocatalytic activity of cobalt oxide (CoO) is the highest, which not only exhibits excellent electrocatalytic oxygen evolution, but also exhibits some electrocatalytic hydrogen evolution. On the other hand, the influence of different nickel and cobalt ratios on the electrocatalytic activity was investigated by doping nickel elements, and it was found that the original Co-MOF had the highest electrocatalytic activity. In addition, the basic characterization was carried out by TG, XRD a