常压储罐气相区气相缓蚀剂防腐技术研究毕设毕业论文.docx

中国石油大学（华东）本科毕业设计（论文） 本 科 毕 业 设 计（论文） 题 目：常压储罐气相区气相缓蚀剂防腐技术研究 学生姓名： 学 号：1 专业班级：材料化学 常压储罐气相区气相缓蚀剂防腐技术研究 摘 要 我国某油田联合站常压储罐罐顶腐蚀严重，针对气相区罐体的防护方式单一，效果有限，本课题首次提出将气相缓蚀剂应用到常压储罐气相区。气相区腐蚀挂片实验测得三个联合站腐蚀速率排序为：三号联合站(0.1025 mm/a)二号联合站(0.0349 mm/a)一号联合站(0.0212 mm/a)；腐蚀挂片实验和电化学实验评价了四种气相缓蚀剂，实验结果表明缓蚀效率从大到小依次是苯甲酸铵亚硝酸二环己胺1-羟基苯并三氮唑 3-氨基-1,2,4三唑，从安全、环保和经济角度考虑，亚硝酸二环己胺为最优选择；进而通过喷雾实验探究发现，三号联气相区的最佳防腐工艺是使用200 ppm的亚硝酸二环己胺溶液间隔24 h喷雾一次。 关键词：气相缓蚀剂；腐蚀实验；储罐气相区；雾化技术  Research on corrosion inhibition of vapor phase inhibitor in atmospheric storage tank vapor phase Abstract The atmospheric storage tank roof of a joint station in China is seriously corroded. The protective method of the tank vapor phase is single and limited. The vapor phase inhibitor is applied to the vapor phase of atmospheric storage tank for the first time. The order of vapor phase corrosion rate of three joint stations is No.3 joint station (0.1025 mm/a) No.2 joint station (0.0349 mm/a) No.1 joint station (0.0212 mm/a). Four commonly used vapor phase inhibitors were evaluated by both corrosion experiments and electrochemical experiments. The experimental results showed that the inhibition efficiency in the order of large to small is benzoic acid ammonium, 1-Hydroxybenzotriazole, dicyclohexyl nitrate and 3-amino-1,2,4-triazole. From the perspective of safety, environmental protection and economy, dicyclohexyl nitrate is the best choice. The optimal concentration of dicyclohexyl nitrate was 200 ppm and the optimal time interval was 24 hours by the spray experiment to protect the vapor phase area of No.3 joint station. Keywords：Vapor phase inhibitor；Corrosion experiment；The vapor zone of the tank  目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc485324002 第1章 绪论 PAGEREF _Toc485324002 \h 1 HYPERLINK \l _Toc485324003 1.1 气相缓蚀剂概述 PAGEREF _Toc485324003 \h 1 HYPERLINK \l _Toc485324004 1.1.1 气相缓蚀剂的定义 PAGEREF _Toc485324004 \h 1 HYPERLINK \l _Toc485324005 1.1.2 气相缓蚀剂分类 PAGEREF _Toc485324005 \h 1 HYPERLINK \l _Toc485324006 1.2 气相