微球负载缓蚀剂型自修复涂层的制备及性能研究毕设毕业论文.docx

本 科 毕 业 设 计（论文） 题 目：微球负载缓蚀剂型自修复涂层的制备 及性能研究 专业班级：材料物理 2014年6月20日 中国石油大学（华东）本科毕业设计（论文） 微球负载缓蚀剂型自修复涂层的制备及性能研究 摘 要 涂层防护是目前防止金属腐蚀最有效的方法之一。然而，防腐涂料在使用过程中内部会产生微裂纹，这会降低涂层的防护效果。具有自修复功能的涂层可以在微裂纹形成早期修复裂纹，其中微球负载缓蚀剂型自修复涂层是常见自修复涂层。 本文通过低压渗透法将三种类型缓蚀剂（咪唑、1,2,4三氮唑、苯并三氮唑）负载到多孔二氧化硅微球中，采用热重分析试验测量微球中缓蚀剂的负载量，结果表明，微球中三种缓蚀剂的负载量分别为16.34wt%、18.07wt%、33.87wt%；然后将负载缓蚀剂的二氧化硅微球加入到丙烯酸聚氨酯中，以Q235钢材作为基体材料，利用划痕模拟微裂纹，通过划痕浸泡试验考察微球负载缓蚀剂型自修复涂层的宏观自修复性能，通过动电位极化曲线和交流阻抗考察微球负载缓蚀剂自修复涂层的对涂层缺陷的愈合作用。结果表明，相比于对比试样，掺杂负载BTA微球的涂层具有较小的自腐蚀电流密度和更大的电荷转移阻抗，说明当涂层内部产生微裂纹时，暴露出来的微球对微裂纹有一定愈合作用，从而保护涂层缺陷处的铁基体材料。 关键词：多孔二氧化硅微球；腐蚀；缓蚀剂；负载；自修复；涂层  Preparation and properties of self-healing coating microspheres load inhibitor type Abstract Coating protection is one of the most effective way to prevent metal corrosion. However, micro cracks will appear in the course of the use of anti-corrosion coating, which will reduce the protective effect of the coating. The coating with self-healing function can be repaired in early stage of micro crack, and the microsphere loaded inhibitor self-healing coating is one of most common self-healing coating. In this paper, three types of corrosion inhibitor be used low osmosis (imidazole 1,2,4-triazole and BTA) load into the porous silica microspheres, thermal gravimetric analysis was used to measure the load of the corrosion inhibitor in the microspheres. The results show that the load percentage of three kinds of inhibitors are 16.34wt%, 18.07wt%, 33.87wt%; Then add the silica microspheres of the load inhibitors to the acrylic acid polyurethane, taking Q235 steel as matrix material, manufacturing scratches are used to simulate the micro cracks, through scratch immersion test to investigated the macro self-healing properties of the self-healing coating, The healing effect of the self-healing coating on the coating defects was investigated by using the dynamic potential polarization curves and AC impedance. The results show that compared to the contrast specimen, doping load BTA coating microspher