预富集-石墨炉原子吸收法连续测定饮料中痕量铅和镉-食品科学.PDFVIP

※分析检测 食品科学 2010, Vol. 31, No. 22 431 陈学泽，苏燕艳，杨 蓉 ( 中南林业科技大学理学院，湖南 长沙 410004) ：建立一种连续测定饮料中痕量铅和镉的新方法。以吡咯烷二硫代氨基甲酸铵(APDC) 为配位剂，用活性 炭在 pH4.0 ～7.0 的条件下捕集、抽滤分离Pb-APDC 、Cd-APDC 配合物，然后用 1mL 洗脱液(HNO3 质量分数为 0.2% 、NH4H2PO4 质量浓度为 10g/L)洗脱，超声振荡 5min 后得可直接上机测定的悬浊液。结果表明：在 100mL 饮 料样品中 Pb 、Cd 的特征质量分别为2.50 ×10-12g 和 6.94 × 10-13g 。当n=6 时，样品测定的铅和镉的标准偏差为 0.0018～0.0055 ，相对标准偏差为3.04%～6.12% ，加标回收率为97.9%～107.0%。该方法具有较高的准确率和富 集效率、快速简单、灵敏可靠，结果较为理想。可用于测定饮料中痕量的铅和镉。 ：预富集；活性炭；石墨炉原子吸收法；铅；镉； Determination of Lead and Cadmium in Beverage by Using Graphite Furnace Atomic Absorption Spectrometry after Pre-concentration CHEN Xue-ze ，SU Yan-yan，YANG Rong (College of Science, Central South Forestry and Technology University, Changsha 410004, China) Abstract：A method was developed for the determination of lead and cadmium in beverage by graphite furnace atomic absorption spectrometry(GFAAS) after pre-concentration. The trace lead and cadmium ions was chelated with ammonium pyrrolidine dithio carbamate (APDC), and fixed on active carbon at pH 4.0 －7.0. Then the active carbon was collected on through vacuum filtration, washed with 1ml of diammoniumhy drogenosphate solution (10 g/L) containing 0.2% nitric acid, and the suspension was directly used for the determination by GFAAS. Concentration of lead and cadmium in beverage samples was -12 -13 2.50 ×10 g, 6.94 ×10 g respectively, with the relative standard deviation(RSD) from 3.04% to 6.21% and spike recoveries from 97.9% to 107.0%. This method could be used to determinate trace heavy metal in beverage. Key words ：preconcentration ；active carbon ；graphite furnace atomic absorp