(TiB+TiC)Ti基复合材料的制备、组织与性能研究材料加工工程专业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 II II Abstract In this paper, (TiB+TiC)/Ti matrix composites were obtained by metal powder injection molding (Metal Injection Molding, MIM) and cast in-situ synthesis. In the MIM process, the selection and proportion of the powder and binder, preparation of feedstock, injection molding, debinding, sintering and other processes were studied. For cast in-situ synthesis, microstructure and properties of the materials were researched . The B4C powder of high purity was mixed into Ti powder by the mass fraction of 2.4%, and then mixed with paraffin-based binder system to be made into tempered homogeneous and liquid feedstock, and then granulating. When mixing, stearic acid (SA) was added as a surfactant to improve the wettability of the powder binder. In the injection process, the mold temperature was 40℃, injection pressure was 150MPa, holding pressure was 120MPa, injection temperature was 140℃, then degreased at room temperature by trichloroethane, carbon disulfide, and gasoline which have an average of debinding ratio is 56.4%, 65.3%, 63.4% respectively, When the weight of sample was no longer change, the time was 60h, 30h, 20h respectively. After the process of degreasing, the result of fracture analysis showed that the majority of forming blanks within the binder was removed, the channel was opened between the powders, and the pores was formed. When vacuum sintering, vacuum was 1×10-2 Mpa or more, the temperature was firstly heated to 200 ℃ by 10℃/min, heat preservation for 5min and then rose to 550℃ by 2.3℃/min, heat preservation for 20min, then the residual binder would be completely removed from the system. Continue to heat up, and finally to 1240 ℃, heat preservation for 40min, 60min, 60min at 800 ℃, 1000℃, 1240℃ respectively, then followed by slow cooling the samples with the furnace. B4C mass fraction of titanium in the share were 2.5%, 2.8%, 2.9%, with button-type non-self-consumable electrode melting furnace smelting