(TiBw+TiCp)Ti复合材料的制备及热变形研究材料工程专业论文.docxVIP

哈尔滨工业大学工学工程硕士学位论文 哈尔滨工业大学工学工程硕士学位论文 - - II - Abstract In order to evaluate the synergistic strengthening effect of hybrid TiC particle(TiCp) and TiB whisker(TiBw) of titanium matrix composites (TMCs), in-situ 10vol.%(TiBw+TiCp)/Ti composites with different TiBw/TiCp ratios of 10:0, 8:2, 5:5, 2:8, and 0:10, respectively, were prepared by reactive hot processing of Ti-B4C-C. Hot extrusion and rolling deformation were performed to partial composites. DSC experiment was carried out to confirm the feasibilityof the designed reactions during the sintering process. The XRD, SEM and TEM were performed to study the microstructure of the prepared composites. Room and high temperature tensile tests were performed to investigate the strengthening effect. By thermodynamic analyses, together with DSC experiment result, the designed in-situ (TiB+TiC)/Ti composites could be fabricated utilizing the reactions of Ti-B4C and Ti-C systerm, and the ratio of TiB/TiC could be controlled by adjusting the added weight of B4C and C raw materials. Microstructure observation shows that TiB phase is rod-like whisker, while TiC phase is equiaxed particle; both of TiBw phase and TiCp phase are uniformly distributed in pure Ti matrix. TiCp can be divided into two groups: one part with a diameter about 2μm formed from the reaction between Ti and C, the other part with a diameter smaller than 0.5μm formed by the reaction between Ti and B4C. Mechanical property results show that the tensile strength and modulus of the composites are obviously improved; however, their ductility is decreased, compared to unreinforced pure Ti. Fortunately, both the strength and the ductility can be remarkably increased by subsequently treatement such as extrusion and rolling. The hybrid strengthening effect of in-situ (TiBw+TiCp)/Ti composite can be achieved to be optimal as TiBw/TiCp =5:5，and the ultimate tensile strength (UTS) and modulus of this composite were increased by 46.88% and 20% than that of pure Ti, respec